Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks

N J Burke; A D Burrows; M F Mahon; L S Pritchard

doi:10.1039/b309884b

Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks

N J Burke, A D Burrows, M F Mahon, L S Pritchard

Department of Chemistry

Research output: Contribution to journal › Article

8 Citations (Scopus)

Abstract

The crystal structures of two hydrogen-bonded adducts containing omicron-bromoterephthalate have been determined and shown to be virtually identical to those of their terephthalate analogues. Consequently, the strategy of manipulating the relative orientation of the carboxylate groups by adding a bromine atom to terephthalate, which has previously been used to give metal-organic frameworks with predictable structure, can be frustrated with the observation of disorder in the bromine position.

Original language	English
Pages (from-to)	355-357
Number of pages	3
Journal	CrystEngComm
Volume	5
DOIs	https://doi.org/10.1039/b309884b
Publication status	Published - 2003

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Burke, N. J., Burrows, A. D., Mahon, M. F., & Pritchard, L. S. (2003). Disorder within dicarboxylates and supramolecular structural control in hydrogen-bonded networks. CrystEngComm, 5, 355-357. https://doi.org/10.1039/b309884b

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N2 - The crystal structures of two hydrogen-bonded adducts containing omicron-bromoterephthalate have been determined and shown to be virtually identical to those of their terephthalate analogues. Consequently, the strategy of manipulating the relative orientation of the carboxylate groups by adding a bromine atom to terephthalate, which has previously been used to give metal-organic frameworks with predictable structure, can be frustrated with the observation of disorder in the bromine position.

AB - The crystal structures of two hydrogen-bonded adducts containing omicron-bromoterephthalate have been determined and shown to be virtually identical to those of their terephthalate analogues. Consequently, the strategy of manipulating the relative orientation of the carboxylate groups by adding a bromine atom to terephthalate, which has previously been used to give metal-organic frameworks with predictable structure, can be frustrated with the observation of disorder in the bromine position.

U2 - 10.1039/b309884b

DO - 10.1039/b309884b

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