Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Qianlong Wang; Alex Madsen; John R. Owen; Mark T. Weller

doi:10.1039/c3cc38897b

Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Qianlong Wang, Alex Madsen, John R. Owen, Mark T. Weller

Department of Chemistry

University of Southampton

Research output: Contribution to journal › Article › peer-review

17 Citations (SciVal)

Abstract

Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.

Original language	English
Pages (from-to)	2121-2123
Journal	Chemical Communications
Volume	49
Issue number	21
Early online date	4 Feb 2013
DOIs	https://doi.org/10.1039/c3cc38897b
Publication status	Published - 14 Mar 2013

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abstract = "Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.",

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AU - Wang, Qianlong

AU - Madsen, Alex

AU - Owen, John R.

AU - Weller, Mark T.

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N2 - Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.

AB - Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.

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Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Abstract

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