Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Qianlong Wang; Alex Madsen; John R. Owen; Mark T. Weller

doi:10.1039/c3cc38897b

Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Qianlong Wang, Alex Madsen, John R. Owen, Mark T. Weller

Department of Chemistry

University of Southampton

Research output: Contribution to journal › Article › peer-review

17 Citations (SciVal)

Abstract

Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.

Original language	English
Pages (from-to)	2121-2123
Journal	Chemical Communications
Volume	49
Issue number	21
Early online date	4 Feb 2013
DOIs	https://doi.org/10.1039/c3cc38897b
Publication status	Published - 14 Mar 2013

Access to Document

10.1039/c3cc38897b

Cite this

@article{2266883308f24e638eec4f4338761438,

title = "Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials",

abstract = "Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.",

author = "Qianlong Wang and Alex Madsen and Owen, {John R.} and Weller, {Mark T.}",

year = "2013",

month = mar,

day = "14",

doi = "10.1039/c3cc38897b",

language = "English",

volume = "49",

pages = "2121--2123",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "21",

}

TY - JOUR

T1 - Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

AU - Wang, Qianlong

AU - Madsen, Alex

AU - Owen, John R.

AU - Weller, Mark T.

PY - 2013/3/14

Y1 - 2013/3/14

N2 - Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.

AB - Synthesis under hydrofluorothermal conditions produces new iron, manganese and vanadium fluorosulfates; these include the isomorphous Na(3)M(III)F(2)(SO(4))(2), M = V, Mn, Fe, with a sheet-like structure formed of linked M(III)F(2)O(4) and SO(4) polyhedra separated by sodium ions which may be extracted electrochemically at potentials of >3.5 V.

UR - http://www.scopus.com/inward/record.url?scp=84874041715&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1039/c3cc38897b

U2 - 10.1039/c3cc38897b

DO - 10.1039/c3cc38897b

M3 - Article

C2 - 23389338

SN - 1359-7345

VL - 49

SP - 2121

EP - 2123

JO - Chemical Communications

JF - Chemical Communications

IS - 21

ER -

Direct hydrofluorothermal synthesis of sodium transition metal fluorosulfates as possible Na-ion battery cathode materials

Abstract

Access to Document

Other files and links

Fingerprint

Cite this