Direct evidence for alkyne coupling to the interstitial carbon in [Ru 4H2(C)(CO)12]; crystal and molecular structure of [Ru4H(CO)12(CCPhCHPh)]

Tom Dutton; Brian F.G. Johnson; Jack Lewis; Steven M. Owen; Paul R. Raithby

doi:10.1039/C39880001423

Direct evidence for alkyne coupling to the interstitial carbon in [Ru ₄H₂(C)(CO)₁₂]; crystal and molecular structure of [Ru₄H(CO)₁₂(CCPhCHPh)]

Tom Dutton, Brian F.G. Johnson, Jack Lewis, Steven M. Owen, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of the 'butterfly' cluster [Ru₄H ₂(C)(CO)₁₂] with PhCCPh, in hexane, gives [Ru ₄H(CO)₁₂(CCPhCHPh)] in which direct coupling between the alkyne and the carbide occurs, and X-ray analysis of this product indicates that the organic fragment co-ordinates to the metal framework in a manner reminiscent of an allyl group.

Original language	English
Pages (from-to)	1423-1424
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	21
DOIs	https://doi.org/10.1039/C39880001423
Publication status	Published - 31 Dec 1988

ASJC Scopus subject areas

Molecular Medicine

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title = "Direct evidence for alkyne coupling to the interstitial carbon in [Ru 4H2(C)(CO)12]; crystal and molecular structure of [Ru4H(CO)12(CCPhCHPh)]",

abstract = "The reaction of the 'butterfly' cluster [Ru4H 2(C)(CO)12] with PhCCPh, in hexane, gives [Ru 4H(CO)12(CCPhCHPh)] in which direct coupling between the alkyne and the carbide occurs, and X-ray analysis of this product indicates that the organic fragment co-ordinates to the metal framework in a manner reminiscent of an allyl group.",

author = "Tom Dutton and Johnson, \{Brian F.G.\} and Jack Lewis and Owen, \{Steven M.\} and Raithby, \{Paul R.\}",

year = "1988",

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doi = "10.1039/C39880001423",

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T1 - Direct evidence for alkyne coupling to the interstitial carbon in [Ru 4H2(C)(CO)12]; crystal and molecular structure of [Ru4H(CO)12(CCPhCHPh)]

AU - Dutton, Tom

AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Owen, Steven M.

AU - Raithby, Paul R.

PY - 1988/12/31

Y1 - 1988/12/31

N2 - The reaction of the 'butterfly' cluster [Ru4H 2(C)(CO)12] with PhCCPh, in hexane, gives [Ru 4H(CO)12(CCPhCHPh)] in which direct coupling between the alkyne and the carbide occurs, and X-ray analysis of this product indicates that the organic fragment co-ordinates to the metal framework in a manner reminiscent of an allyl group.

AB - The reaction of the 'butterfly' cluster [Ru4H 2(C)(CO)12] with PhCCPh, in hexane, gives [Ru 4H(CO)12(CCPhCHPh)] in which direct coupling between the alkyne and the carbide occurs, and X-ray analysis of this product indicates that the organic fragment co-ordinates to the metal framework in a manner reminiscent of an allyl group.

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U2 - 10.1039/C39880001423

DO - 10.1039/C39880001423

M3 - Article

AN - SCOPUS:37049085913

SN - 0022-4936

SP - 1423

EP - 1424

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 21

ER -

Direct evidence for alkyne coupling to the interstitial carbon in [Ru ₄H₂(C)(CO)₁₂]; crystal and molecular structure of [Ru₄H(CO)₁₂(CCPhCHPh)]

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