Direct and transfer hydrogenation of ketones and imines with a ruthenium N-heterocyclic carbene complex

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Abstract

The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes)(PPh3)2CO(H)2 (IMes = 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.
LanguageEnglish
Pages591-594
Number of pages4
JournalAdvanced Synthesis & Catalysis
Volume347
Issue number4
StatusPublished - 2005

Fingerprint

Imines
Ruthenium
Ketones
Hydrogenation
Catalysts
carbene

Keywords

  • Ketones Role
  • imines and alkenes)
  • Imines
  • Hydrogenation (alc. oxidn.
  • RCT (Reactant)
  • alc. oxidn.
  • Alcohols
  • ruthenium nitrogen heterocyclic carbene complex catalyzed hydrogenation
  • ketone and imine redn. via ruthenium N-heterocyclic carbene complex catalyzed direct and transfer hydrogenation between alcs.
  • Hydrogenation (transfer
  • RACT (Reactant or reagent) (alc. oxidn.
  • alc oxidn ketone imine redn direct transfer hydrogenation
  • ketones

Cite this

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title = "Direct and transfer hydrogenation of ketones and imines with a ruthenium N-heterocyclic carbene complex",
abstract = "The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes)(PPh3)2CO(H)2 (IMes = 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.",
keywords = "Ketones Role, imines and alkenes), Imines, Hydrogenation (alc. oxidn., RCT (Reactant), alc. oxidn., Alcohols, ruthenium nitrogen heterocyclic carbene complex catalyzed hydrogenation, ketone and imine redn. via ruthenium N-heterocyclic carbene complex catalyzed direct and transfer hydrogenation between alcs., Hydrogenation (transfer, RACT (Reactant or reagent) (alc. oxidn., alc oxidn ketone imine redn direct transfer hydrogenation, ketones",
author = "Suzanne Burling and Whittlesey, {Michael K} and Williams, {Jonathan M J}",
year = "2005",
language = "English",
volume = "347",
pages = "591--594",
journal = "Advanced Synthesis & Catalysis",
issn = "1615-4150",
publisher = "Wiley-VCH Verlag",
number = "4",

}

TY - JOUR

T1 - Direct and transfer hydrogenation of ketones and imines with a ruthenium N-heterocyclic carbene complex

AU - Burling,Suzanne

AU - Whittlesey,Michael K

AU - Williams,Jonathan M J

PY - 2005

Y1 - 2005

N2 - The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes)(PPh3)2CO(H)2 (IMes = 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.

AB - The dihydride ruthenium N-heterocyclic carbene complex Ru(IMes)(PPh3)2CO(H)2 (IMes = 1,3-dimesityl-1,3-dihydro-2H-imidazol-2-ylidene) is an efficient catalyst for both direct hydrogenation and transfer hydrogenation of ketones and imines, in the absence of base.

KW - Ketones Role

KW - imines and alkenes)

KW - Imines

KW - Hydrogenation (alc. oxidn.

KW - RCT (Reactant)

KW - alc. oxidn.

KW - Alcohols

KW - ruthenium nitrogen heterocyclic carbene complex catalyzed hydrogenation

KW - ketone and imine redn. via ruthenium N-heterocyclic carbene complex catalyzed direct and transfer hydrogenation between alcs.

KW - Hydrogenation (transfer

KW - RACT (Reactant or reagent) (alc. oxidn.

KW - alc oxidn ketone imine redn direct transfer hydrogenation

KW - ketones

M3 - Article

VL - 347

SP - 591

EP - 594

JO - Advanced Synthesis & Catalysis

T2 - Advanced Synthesis & Catalysis

JF - Advanced Synthesis & Catalysis

SN - 1615-4150

IS - 4

ER -