Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

Andrew D Burrows; Christopher G Frost; Mary F Mahon; Paul R Raithby; C L Renouf; C Richardson; Anna Stevenson

doi:10.1039/c0cc00646g

Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

Andrew D Burrows, Christopher G Frost, Mary F Mahon, Paul R Raithby, C L Renouf, C Richardson, Anna Stevenson

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (SciVal)

Abstract

The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

Original language	English
Pages (from-to)	5067-5069
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	28
Early online date	7 Jun 2010
DOIs	https://doi.org/10.1039/c0cc00646g
Publication status	Published - 28 Jul 2010

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title = "Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks",

abstract = "The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.",

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AU - Burrows, Andrew D

AU - Frost, Christopher G

AU - Mahon, Mary F

AU - Raithby, Paul R

AU - Renouf, C L

AU - Richardson, C

AU - Stevenson, Anna

PY - 2010/7/28

Y1 - 2010/7/28

N2 - The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

AB - The Group 13 metal complexes [M(L-2)(3)], where M is Al or Ga and L-2 is 1,3-di(4-pyridyl)-1,3-propanedionato, are hexatopic metalloligands that have been used to prepare mixed-metalorganic frameworks containing interpenetrated primitive cubic networks. In contrast, the europium complex [Eu(HL2)(3)-(H2L2)]Cl-4 center dot EtOH forms a hydrogen-bonded network following partial protonation of the pyridyl groups.

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IS - 28

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Dipyridyl β-diketonate complexes: versatile polydentate metalloligands for metal-organic frameworks and hydrogen-bonded networks

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