[(DippNH)2Al(μ-NHDipp)2Li·thf] and [thf·Li(μ-NHCy)3Sn(μ-NHCy) 3Li·thf]·C6H5Me, potential building blocks for heterometallic imido compounds (Dipp = 2,6-Pri2C6H3)

Michael A. Beswick; Nick Choi; Christopher N. Harmer; Mary McPartlin; Marta E.G. Mosquera; Paul R. Raithby; Mustafa Tombul; Dominic S. Wright

doi:10.1039/a802590h

[(DippNH)₂Al(μ-NHDipp)₂Li·thf] and [thf·Li(μ-NHCy)₃Sn(μ-NHCy) ₃Li·thf]·C₆H₅Me, potential building blocks for heterometallic imido compounds (Dipp = 2,6-Prⁱ₂C₆H₃)

Michael A. Beswick, Nick Choi, Christopher N. Harmer, Mary McPartlin, Marta E.G. Mosquera, Paul R. Raithby, Mustafa Tombul, Dominic S. Wright

Research output: Contribution to journal › Article › peer-review

17 Citations (SciVal)

Abstract

[(DippNH)₂Al(μ-NHDipp)₂Li·thf] 1 and [thf·Li(μ-NHCy)₃Sn(μ-NHCy) ₃Li·thf]·C₆H₅Me 2 are produced from the reactions of AlCl₃ and SnCl₄ or MeAlCl₂ and MeSn(NMe₂)₃ with the apporopriate primary amido lithium precursors [RNHLi; R = 2,6-Prⁱ₂C₆H₃ (Dipp), C₆H₁₁ (Cy)]; both complexes have ion-paired structures in the solid state with the retention of potentially reactive N-H functionality providing precursors for heterometallic species containing [M(NR)_x(NHR)_{n - x}]^{(1 +x)-} anions (M = Al, n = 4; M = Sn, n = 6).

Original language	English
Pages (from-to)	1383-1384
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/a802590h
Publication status	Published - 7 Jul 1998

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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Beswick, M. A., Choi, N., Harmer, C. N., McPartlin, M., Mosquera, M. E. G., Raithby, P. R., Tombul, M., & Wright, D. S. (1998). [(DippNH)₂Al(μ-NHDipp)₂Li·thf] and [thf·Li(μ-NHCy)₃Sn(μ-NHCy) ₃Li·thf]·C₆H₅Me, potential building blocks for heterometallic imido compounds (Dipp = 2,6-Prⁱ₂C₆H₃). Chemical Communications, (13), 1383-1384. https://doi.org/10.1039/a802590h

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title = "[(DippNH)2Al(μ-NHDipp)2Li·thf] and [thf·Li(μ-NHCy)3Sn(μ-NHCy) 3Li·thf]·C6H5Me, potential building blocks for heterometallic imido compounds (Dipp = 2,6-Pri2C6H3)",

abstract = "[(DippNH)2Al(μ-NHDipp)2Li·thf] 1 and [thf·Li(μ-NHCy)3Sn(μ-NHCy) 3Li·thf]·C6H5Me 2 are produced from the reactions of AlCl3 and SnCl4 or MeAlCl2 and MeSn(NMe2)3 with the apporopriate primary amido lithium precursors [RNHLi; R = 2,6-Pri2C6H3 (Dipp), C6H11 (Cy)]; both complexes have ion-paired structures in the solid state with the retention of potentially reactive N-H functionality providing precursors for heterometallic species containing [M(NR)x(NHR)n - x](1 +x)- anions (M = Al, n = 4; M = Sn, n = 6).",

author = "Beswick, {Michael A.} and Nick Choi and Harmer, {Christopher N.} and Mary McPartlin and Mosquera, {Marta E.G.} and Raithby, {Paul R.} and Mustafa Tombul and Wright, {Dominic S.}",

year = "1998",

month = jul,

day = "7",

doi = "10.1039/a802590h",

language = "English",

pages = "1383--1384",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "13",

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TY - JOUR

T1 - [(DippNH)2Al(μ-NHDipp)2Li·thf] and [thf·Li(μ-NHCy)3Sn(μ-NHCy) 3Li·thf]·C6H5Me, potential building blocks for heterometallic imido compounds (Dipp = 2,6-Pri2C6H3)

AU - Beswick, Michael A.

AU - Choi, Nick

AU - Harmer, Christopher N.

AU - McPartlin, Mary

AU - Mosquera, Marta E.G.

AU - Raithby, Paul R.

AU - Tombul, Mustafa

AU - Wright, Dominic S.

PY - 1998/7/7

Y1 - 1998/7/7

N2 - [(DippNH)2Al(μ-NHDipp)2Li·thf] 1 and [thf·Li(μ-NHCy)3Sn(μ-NHCy) 3Li·thf]·C6H5Me 2 are produced from the reactions of AlCl3 and SnCl4 or MeAlCl2 and MeSn(NMe2)3 with the apporopriate primary amido lithium precursors [RNHLi; R = 2,6-Pri2C6H3 (Dipp), C6H11 (Cy)]; both complexes have ion-paired structures in the solid state with the retention of potentially reactive N-H functionality providing precursors for heterometallic species containing [M(NR)x(NHR)n - x](1 +x)- anions (M = Al, n = 4; M = Sn, n = 6).

AB - [(DippNH)2Al(μ-NHDipp)2Li·thf] 1 and [thf·Li(μ-NHCy)3Sn(μ-NHCy) 3Li·thf]·C6H5Me 2 are produced from the reactions of AlCl3 and SnCl4 or MeAlCl2 and MeSn(NMe2)3 with the apporopriate primary amido lithium precursors [RNHLi; R = 2,6-Pri2C6H3 (Dipp), C6H11 (Cy)]; both complexes have ion-paired structures in the solid state with the retention of potentially reactive N-H functionality providing precursors for heterometallic species containing [M(NR)x(NHR)n - x](1 +x)- anions (M = Al, n = 4; M = Sn, n = 6).

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U2 - 10.1039/a802590h

DO - 10.1039/a802590h

M3 - Article

AN - SCOPUS:0001813367

SN - 1359-7345

SP - 1383

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JO - Chemical Communications

JF - Chemical Communications

IS - 13

ER -

[(DippNH)₂Al(μ-NHDipp)₂Li·thf] and [thf·Li(μ-NHCy)₃Sn(μ-NHCy) ₃Li·thf]·C₆H₅Me, potential building blocks for heterometallic imido compounds (Dipp = 2,6-Prⁱ₂C₆H₃)

Abstract

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