Dimerization of indanediyl fragments: An alkene analogue for group 13?

Michael S. Hill; Peter B. Hitchcock; Ruti Pongtavornpinyo

doi:10.1002/anie.200500764

Dimerization of indanediyl fragments: An alkene analogue for group 13?

Michael S. Hill
, Peter B. Hitchcock
, Ruti Pongtavornpinyo

Imperial College London
University of Sussex

Research output: Contribution to journal › Article › peer-review

52 Citations (SciVal)

Abstract

(Figure Presented) A β-diketiminate complex of indium, [ln{N(2,4,6-Me₃C₆H₂)C(Me)}₂CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C_2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.

Original language	English
Pages (from-to)	4231-4235
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	27
DOIs	https://doi.org/10.1002/anie.200500764
Publication status	Published - 4 Jul 2005

Keywords

Carbenoids
Group 13 elements
Indium
Metal-metal interactions
Multiple bonds

ASJC Scopus subject areas

Catalysis
General Chemistry

Access to Document

10.1002/anie.200500764

Cite this

@article{339eae8a566d4bd5b0d2ed21de174e60,

title = "Dimerization of indanediyl fragments: An alkene analogue for group 13?",

abstract = "(Figure Presented) A β-diketiminate complex of indium, [ln\{N(2,4,6-Me3C6H2)C(Me)\}2CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.",

keywords = "Carbenoids, Group 13 elements, Indium, Metal-metal interactions, Multiple bonds",

author = "Hill, \{Michael S.\} and Hitchcock, \{Peter B.\} and Ruti Pongtavornpinyo",

year = "2005",

month = jul,

day = "4",

doi = "10.1002/anie.200500764",

language = "English",

volume = "44",

pages = "4231--4235",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Inc.",

number = "27",

}

TY - JOUR

T1 - Dimerization of indanediyl fragments

T2 - An alkene analogue for group 13?

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Pongtavornpinyo, Ruti

PY - 2005/7/4

Y1 - 2005/7/4

N2 - (Figure Presented) A β-diketiminate complex of indium, [ln{N(2,4,6-Me3C6H2)C(Me)}2CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.

AB - (Figure Presented) A β-diketiminate complex of indium, [ln{N(2,4,6-Me3C6H2)C(Me)}2CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.

KW - Carbenoids

KW - Group 13 elements

KW - Indium

KW - Metal-metal interactions

KW - Multiple bonds

UR - https://www.scopus.com/pages/publications/22144487401

U2 - 10.1002/anie.200500764

DO - 10.1002/anie.200500764

M3 - Article

AN - SCOPUS:22144487401

SN - 1433-7851

VL - 44

SP - 4231

EP - 4235

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 27

ER -

Dimerization of indanediyl fragments: An alkene analogue for group 13?

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this