Dimerization of indanediyl fragments: An alkene analogue for group 13?

Michael S. Hill; Peter B. Hitchcock; Ruti Pongtavornpinyo

doi:10.1002/anie.200500764

Dimerization of indanediyl fragments: An alkene analogue for group 13?

Michael S. Hill, Peter B. Hitchcock, Ruti Pongtavornpinyo

Research output: Contribution to journal › Article › peer-review

48 Citations (SciVal)

Abstract

(Figure Presented) A β-diketiminate complex of indium, [ln{N(2,4,6-Me₃C₆H₂)C(Me)}₂CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C_2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.

Original language	English
Pages (from-to)	4231-4235
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	27
DOIs	https://doi.org/10.1002/anie.200500764
Publication status	Published - 4 Jul 2005

Keywords

Carbenoids
Group 13 elements
Indium
Metal-metal interactions
Multiple bonds

ASJC Scopus subject areas

Catalysis
General Chemistry

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title = "Dimerization of indanediyl fragments: An alkene analogue for group 13?",

abstract = "(Figure Presented) A β-diketiminate complex of indium, [ln{N(2,4,6-Me3C6H2)C(Me)}2CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.",

keywords = "Carbenoids, Group 13 elements, Indium, Metal-metal interactions, Multiple bonds",

author = "Hill, {Michael S.} and Hitchcock, {Peter B.} and Ruti Pongtavornpinyo",

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T1 - Dimerization of indanediyl fragments

T2 - An alkene analogue for group 13?

AU - Hill, Michael S.

AU - Hitchcock, Peter B.

AU - Pongtavornpinyo, Ruti

PY - 2005/7/4

Y1 - 2005/7/4

N2 - (Figure Presented) A β-diketiminate complex of indium, [ln{N(2,4,6-Me3C6H2)C(Me)}2CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.

AB - (Figure Presented) A β-diketiminate complex of indium, [ln{N(2,4,6-Me3C6H2)C(Me)}2CH], dimerizes in the solid state (see space-filling model) to provide an indium species that is formally isoelectronic to the historically significant bis(stannane)diyls. A direct In - In bond is formed yielding a centrosymmetric dimer that possesses approximate C2h symmetry with a mutual trans-bent orientation of the N-chelating ligands.

KW - Carbenoids

KW - Group 13 elements

KW - Indium

KW - Metal-metal interactions

KW - Multiple bonds

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JF - Angewandte Chemie - International Edition

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ER -

Dimerization of indanediyl fragments: An alkene analogue for group 13?

Abstract

Keywords

ASJC Scopus subject areas

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