Diels-Alder reaction of furan and fumaryl chloride: X-ray crystal and molecular structure of an oxabicyclo[2.2.1]heptane derivative. Synthesis of reduction products of cis-maneonene-A

Clive L.D. Jennings-White; Andrew B. Holmes; Paul R. Raithby

doi:10.1039/C39790000542

Diels-Alder reaction of furan and fumaryl chloride: X-ray crystal and molecular structure of an oxabicyclo[2.2.1]heptane derivative. Synthesis of reduction products of cis-maneonene-A

Clive L.D. Jennings-White
, Andrew B. Holmes
, Paul R. Raithby

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The addition of fumaryl chloride to furan, followed by hydrolysis and bromolactonisation of the adduct, leads to the bromo-lactone acid (2a) which serves as a precursor for the synthesis of the reduction products (5a), (5b), and (6a) of cis-maneonene-A and of the tosylate (6b) whose X-ray crystal structure has been determined.

Original language	English
Pages (from-to)	542-544
Number of pages	3
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39790000542
Publication status	Published - 31 Dec 1979

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Molecular Medicine

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Diels-Alder reaction of furan and fumaryl chloride: X-ray crystal and molecular structure of an oxabicyclo[2.2.1]heptane derivative. Synthesis of reduction products of cis-maneonene-A. / Jennings-White, Clive L.D.; Holmes, Andrew B.; Raithby, Paul R.
In: Journal of the Chemical Society, Chemical Communications, No. 12, 31.12.1979, p. 542-544.

Research output: Contribution to journal › Article › peer-review

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abstract = "The addition of fumaryl chloride to furan, followed by hydrolysis and bromolactonisation of the adduct, leads to the bromo-lactone acid (2a) which serves as a precursor for the synthesis of the reduction products (5a), (5b), and (6a) of cis-maneonene-A and of the tosylate (6b) whose X-ray crystal structure has been determined.",

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AB - The addition of fumaryl chloride to furan, followed by hydrolysis and bromolactonisation of the adduct, leads to the bromo-lactone acid (2a) which serves as a precursor for the synthesis of the reduction products (5a), (5b), and (6a) of cis-maneonene-A and of the tosylate (6b) whose X-ray crystal structure has been determined.

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Diels-Alder reaction of furan and fumaryl chloride: X-ray crystal and molecular structure of an oxabicyclo[2.2.1]heptane derivative. Synthesis of reduction products of cis-maneonene-A

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