TY - JOUR
T1 - Dichloridodiphenylbis(thiourea-κS)tin(IV)
AU - Sow, Yaya
AU - Diop, Libasse
AU - Molloy, Kieran C.
AU - Kociok-Kohn, Gabriele
PY - 2013/10
Y1 - 2013/10
N2 - The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the molecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The SnIV atom is coordinated by two phenyl groups, two Cl atoms and two thiourea ligands in an all trans octahedral C2Cl2S2 environment. Individual molecules are connected through N-H...Cl hydrogen bonds, leading to a three-dimensional network structure. Intramolecular N-H...Cl hydrogen bonds are also present.
AB - The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the molecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The SnIV atom is coordinated by two phenyl groups, two Cl atoms and two thiourea ligands in an all trans octahedral C2Cl2S2 environment. Individual molecules are connected through N-H...Cl hydrogen bonds, leading to a three-dimensional network structure. Intramolecular N-H...Cl hydrogen bonds are also present.
UR - http://www.scopus.com/inward/record.url?scp=84885165878&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1107/S1600536813024343
U2 - 10.1107/S1600536813024343
DO - 10.1107/S1600536813024343
M3 - Article
SN - 1600-5368
VL - 69
SP - m539-m540
JO - Acta Crystallographica Section E-Structure Reports Online
JF - Acta Crystallographica Section E-Structure Reports Online
IS - 10
ER -