Dichloridodiphenylbis(thiourea-κS)tin(IV)

Yaya Sow, Libasse Diop, Kieran C. Molloy, Gabriele Kociok-Kohn

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

The title compound, [Sn(C6H5)2Cl2(CH4N2S)2], has been obtained from the reaction between Sn(C6H5)2Cl2 and SC(NH2)2. The asymmetric unit consists of one half of the molecular unit, the remainder generated by a twofold rotation axis located along the Cl-Sn-Cl bonds. The SnIV atom is coordinated by two phenyl groups, two Cl atoms and two thiourea ligands in an all trans octahedral C2Cl2S2 environment. Individual molecules are connected through N-H...Cl hydrogen bonds, leading to a three-dimensional network structure. Intramolecular N-H...Cl hydrogen bonds are also present.
Original languageEnglish
Pages (from-to)m539-m540
Number of pages2
JournalActa Crystallographica Section E-Structure Reports Online
Volume69
Issue number10
DOIs
Publication statusPublished - Oct 2013

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Thiourea
Tin
Thioureas
thioureas
tin
Hydrogen bonds
hydrogen bonds
Atoms
atoms
Ligands
ligands
Molecules
molecules

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Dichloridodiphenylbis(thiourea-κS)tin(IV). / Sow, Yaya; Diop, Libasse; Molloy, Kieran C.; Kociok-Kohn, Gabriele.

In: Acta Crystallographica Section E-Structure Reports Online, Vol. 69, No. 10, 10.2013, p. m539-m540.

Research output: Contribution to journalArticle

Sow, Yaya ; Diop, Libasse ; Molloy, Kieran C. ; Kociok-Kohn, Gabriele. / Dichloridodiphenylbis(thiourea-κS)tin(IV). In: Acta Crystallographica Section E-Structure Reports Online. 2013 ; Vol. 69, No. 10. pp. m539-m540.
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