Diaquabis(1,1,4-trimethylthiosemicarbazide)-nickel(II) dinitrate

A D Burrows; R W Harrington; M F Mahon

doi:10.1107/s1600536805002965

Diaquabis(1,1,4-trimethylthiosemicarbazide)-nickel(II) dinitrate

A D Burrows, R W Harrington, M F Mahon

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The determination of the crystal structure of the title compound, [Ni(C4H11N3S)(2)(H2O)(2)](NO3)(2), reveals a distorted octahedral geometry around the Ni centre, which lies on an inversion centre, with water molecules occupying the axial positions. Hydrogen bonding is observed between the 1,1,4-trimethylthiosenticarbazide NH groups and the nitrate anions, and also between the coordinated water molecules and the anions.

Original language	English
Pages (from-to)	M551-M553
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	61
DOIs	https://doi.org/10.1107/s1600536805002965
Publication status	Published - 2005

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title = "Diaquabis(1,1,4-trimethylthiosemicarbazide)-nickel(II) dinitrate",

abstract = "The determination of the crystal structure of the title compound, [Ni(C4H11N3S)(2)(H2O)(2)](NO3)(2), reveals a distorted octahedral geometry around the Ni centre, which lies on an inversion centre, with water molecules occupying the axial positions. Hydrogen bonding is observed between the 1,1,4-trimethylthiosenticarbazide NH groups and the nitrate anions, and also between the coordinated water molecules and the anions.",

author = "Burrows, {A D} and Harrington, {R W} and Mahon, {M F}",

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AU - Burrows, A D

AU - Harrington, R W

AU - Mahon, M F

N1 - ID number: ISI:000227377500063

PY - 2005

Y1 - 2005

N2 - The determination of the crystal structure of the title compound, [Ni(C4H11N3S)(2)(H2O)(2)](NO3)(2), reveals a distorted octahedral geometry around the Ni centre, which lies on an inversion centre, with water molecules occupying the axial positions. Hydrogen bonding is observed between the 1,1,4-trimethylthiosenticarbazide NH groups and the nitrate anions, and also between the coordinated water molecules and the anions.

AB - The determination of the crystal structure of the title compound, [Ni(C4H11N3S)(2)(H2O)(2)](NO3)(2), reveals a distorted octahedral geometry around the Ni centre, which lies on an inversion centre, with water molecules occupying the axial positions. Hydrogen bonding is observed between the 1,1,4-trimethylthiosenticarbazide NH groups and the nitrate anions, and also between the coordinated water molecules and the anions.

U2 - 10.1107/s1600536805002965

DO - 10.1107/s1600536805002965

M3 - Article

SN - 1600-5368

VL - 61

SP - M551-M553

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

ER -

Diaquabis(1,1,4-trimethylthiosemicarbazide)-nickel(II) dinitrate

Abstract

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