Diamidopyrazoles: A new class of anion receptors

Jonathan L. Sessler, Bobbi L. Rubin, Salvatore Camiolo, Won-Seob Cho, G. Dan Pantos, Vincent M. Lynch

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The synthesis of a series of 3,5-diamidopyrazoles is reported. The anion binding properties of these systems were examined via (1)H NMR, UV/Vis and ITC titration techniques. Target compound 2a acts as a selective receptor for phosphate and sulfate anions in DMSO, whereas N-methylated 2b and the unmethylated species 4d show no appreciable binding affinity. Insights into the binding events occurring in solution came from the solid state structures of compounds 2a and 4a, 4b, and 4d, which were deduced from single crystal X-ray diffraction analyses.
Original languageEnglish
Pages (from-to)103-109
Number of pages7
JournalSupramolecular Chemistry
Volume18
Issue number2
DOIs
Publication statusPublished - 1 Apr 2006

Keywords

  • pyrazole
  • anion receptor
  • dihydrogen phosphate
  • hydrogen sulfate
  • methyl orange

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