Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]

Y. Sow; L. Diop; K.C. Molloy; Gabriele Kociok-Kohn

doi:10.1107/S1600536812043462

Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]

Y. Sow, L. Diop, K.C. Molloy, Gabriele Kociok-Kohn

Université Cheikh Anta Diop

Research output: Contribution to journal › Article › peer-review

3 Citations (SciVal)

Abstract

The Sn atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O-H⋯S and C-H⋯ S hydrogen-bonding interactions into a three-dimensional network.

Original language	English
Article number	m1436
Journal	Acta Crystallographica Section E-Structure Reports Online
Volume	68
Issue number	12
DOIs	https://doi.org/10.1107/S1600536812043462
Publication status	Published - Dec 2012

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10.1107/S1600536812043462

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title = "Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]",

abstract = "The Sn atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O-H⋯S and C-H⋯ S hydrogen-bonding interactions into a three-dimensional network.",

author = "Y. Sow and L. Diop and K.C. Molloy and Gabriele Kociok-Kohn",

year = "2012",

month = dec,

doi = "10.1107/S1600536812043462",

language = "English",

volume = "68",

journal = "Acta Crystallographica Section E-Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

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T1 - Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]

AU - Sow, Y.

AU - Diop, L.

AU - Molloy, K.C.

AU - Kociok-Kohn, Gabriele

PY - 2012/12

Y1 - 2012/12

N2 - The Sn atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O-H⋯S and C-H⋯ S hydrogen-bonding interactions into a three-dimensional network.

AB - The Sn atom in the centrosymmetric title complex, [Sn2(CH3)4(NCS)2(OH)2], adopts a distorted trigonal-bipyramidal coordination environment defined by two methyl C atoms and one bridging hydroxide group in the equatorial plane while the other bridging hydroxide group and the N atom of the thiocyanate anion are in the apical >positions. The dinuclear species are linked through O-H⋯S and C-H⋯ S hydrogen-bonding interactions into a three-dimensional network.

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UR - http://dx.doi.org/10.1107/S1600536812043462

U2 - 10.1107/S1600536812043462

DO - 10.1107/S1600536812043462

M3 - Article

AN - SCOPUS:84870902424

SN - 1600-5368

VL - 68

JO - Acta Crystallographica Section E-Structure Reports Online

JF - Acta Crystallographica Section E-Structure Reports Online

IS - 12

M1 - m1436

ER -

Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]

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MC2- X-ray diffraction (XRD)

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Di-μ-hydroxido-bis[dimethyl(thiocyanato-κN)tin(IV)]

Abstract

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MC2- X-ray diffraction (XRD)

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