Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]

A Rifat; M F Mahon; A S Weller

doi:10.1016/s0022-328x(02)01923-x

Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]

A Rifat, M F Mahon, A S Weller

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (SciVal)

Abstract

Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	667
Issue number	1-2
DOIs	https://doi.org/10.1016/s0022-328x(02)01923-x
Publication status	Published - 2003

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ID number: ISI:000181147000001

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Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]. / Rifat, A; Mahon, M F; Weller, A S.
In: Journal of Organometallic Chemistry, Vol. 667, No. 1-2, 2003, p. 1-4.

Research output: Contribution to journal › Article › peer-review

Rifat, A, Mahon, MF & Weller, AS 2003, 'Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]', Journal of Organometallic Chemistry, vol. 667, no. 1-2, pp. 1-4. https://doi.org/10.1016/s0022-328x(02)01923-x

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abstract = "Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.",

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AB - Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.

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Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]

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