Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]

A Rifat; M F Mahon; A S Weller

doi:10.1016/s0022-328x(02)01923-x

Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]

A Rifat, M F Mahon, A S Weller

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Citations (SciVal)

Abstract

Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.

Original language	English
Pages (from-to)	1-4
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	667
Issue number	1-2
DOIs	https://doi.org/10.1016/s0022-328x(02)01923-x
Publication status	Published - 2003

Bibliographical note

ID number: ISI:000181147000001

Access to Document

10.1016/s0022-328x(02)01923-x

Fingerprint

Dive into the research topics of 'Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]'. Together they form a unique fingerprint.

Cite this

Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]. / Rifat, A; Mahon, M F; Weller, A S.
In: Journal of Organometallic Chemistry, Vol. 667, No. 1-2, 2003, p. 1-4.

Research output: Contribution to journal › Article › peer-review

Rifat, A, Mahon, MF & Weller, AS 2003, 'Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]', Journal of Organometallic Chemistry, vol. 667, no. 1-2, pp. 1-4. https://doi.org/10.1016/s0022-328x(02)01923-x

@article{f2e451c98db7447aabf13601ffee9a7a,

title = "Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]",

abstract = "Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.",

author = "A Rifat and Mahon, {M F} and Weller, {A S}",

note = "ID number: ISI:000181147000001",

year = "2003",

doi = "10.1016/s0022-328x(02)01923-x",

language = "English",

volume = "667",

pages = "1--4",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "1-2",

}

TY - JOUR

T1 - Dehydrogenation of cyclohexenes to cyclohexadienes by [(PPh3)(2)Rh](+). The isolation of an intermediate in the dehydrogenation of cyclohexane to benzene: crystal structure of [(eta(4)-C6H8)Rh(PPh3)(2)][closo-CB11H6Br6]

AU - Rifat, A

AU - Mahon, M F

AU - Weller, A S

N1 - ID number: ISI:000181147000001

PY - 2003

Y1 - 2003

N2 - Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.

AB - Treatment of the arene bridged dimer [(PPh3)(2)Rh](2)[closo-CB11H6Br6](2) with eight equivalents of cyclohexene affords [(eta(4)- C6H8)Rh(PPh3)(2)][closo-CB11H6Br6] with the concomitant formation of one equivalent of cyclohexane, while 1-methylcyclohexane and 4-methylcyclohexane both give 2-methylcyclohexa-1,3-diene complexes; all of these products are intermediates in the catalytic dehydrogenation pathway of cyclohexane to benzene. (C) 2002 Elsevier Science B.V. All rights reserved.

U2 - 10.1016/s0022-328x(02)01923-x

DO - 10.1016/s0022-328x(02)01923-x

M3 - Article

SN - 0022-328X

VL - 667

SP - 1

EP - 4

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -