Definitive crystal structures of ortho-, meta- And para-carboranes: Supramolecular structures directed solely by C-H⋯O hydrogen bonding to hmpa (hmpa = hexamethylphosphoramide)

Matthew G. Davidson; Thomas G. Hibbert; Judith A.K. Howard; Angus Mackinnon; Kenneth Wade

doi:10.1039/CC9960002285

Definitive crystal structures of ortho-, meta- And para-carboranes: Supramolecular structures directed solely by C-H⋯O hydrogen bonding to hmpa (hmpa = hexamethylphosphoramide)

Matthew G. Davidson, Thomas G. Hibbert, Judith A.K. Howard, Angus Mackinnon, Kenneth Wade

Durham University

Research output: Contribution to journal › Article › peer-review

141 Citations (SciVal)

Abstract

Cocrystallisation of ortho- meta- and para-carboranes with hmpa (hexamethylphosphoramide) results in the isolation of 1:1 carborane:hmpa adducts which provide the first definitive X-ray structures of the unsubstituted carboranes as part of three very different C-H⋯O hydrogen-bonded supramolecular structures.

Original language	English
Pages (from-to)	2285-2286
Number of pages	2
Journal	Chemical Communications
Issue number	19
DOIs	https://doi.org/10.1039/CC9960002285
Publication status	Published - 1996

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/CC9960002285

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Definitive crystal structures of ortho-, meta- And para-carboranes: Supramolecular structures directed solely by C-H⋯O hydrogen bonding to hmpa (hmpa = hexamethylphosphoramide). / Davidson, Matthew G.; Hibbert, Thomas G.; Howard, Judith A.K. et al.
In: Chemical Communications, No. 19, 1996, p. 2285-2286.

Research output: Contribution to journal › Article › peer-review

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abstract = "Cocrystallisation of ortho- meta- and para-carboranes with hmpa (hexamethylphosphoramide) results in the isolation of 1:1 carborane:hmpa adducts which provide the first definitive X-ray structures of the unsubstituted carboranes as part of three very different C-H⋯O hydrogen-bonded supramolecular structures.",

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AU - Mackinnon, Angus

AU - Wade, Kenneth

PY - 1996

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AB - Cocrystallisation of ortho- meta- and para-carboranes with hmpa (hexamethylphosphoramide) results in the isolation of 1:1 carborane:hmpa adducts which provide the first definitive X-ray structures of the unsubstituted carboranes as part of three very different C-H⋯O hydrogen-bonded supramolecular structures.

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Definitive crystal structures of ortho-, meta- And para-carboranes: Supramolecular structures directed solely by C-H⋯O hydrogen bonding to hmpa (hmpa = hexamethylphosphoramide)

Abstract

ASJC Scopus subject areas

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