Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me2N)3PNHBNP(NMe2)3],O2+(C2B9H12-)2

Matthew G. Davidson; Mark A. Fox; Thomas G. Hibbert; Judith A.K. Howard; Angus Mackinnon; Ivan S. Neretin; Kenneth Wade

doi:10.1039/a903030a

Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me₂N)₃PNHBNP(NMe₂)₃],O²⁺(C₂B₉H₁₂^-)₂

Matthew G. Davidson, Mark A. Fox, Thomas G. Hibbert, Judith A.K. Howard, Angus Mackinnon, Ivan S. Neretin, Kenneth Wade

Department of Chemistry

Durham University

Research output: Contribution to journal › Article › peer-review

69 Citations (SciVal)

Abstract

The structures of the adduct nido-C₂B₁₀H₁₂·HNP(NMe₂)₃ and the borenium salt [(Me₂N)₃PNHBNP(NMe₂)₃]₂O²⁺(C₂B₉H₁₂^-)₂, both obtained from 1,2-C₂B₁₀H₁₂ and HNP(NMe₂)₃, were determined by X-ray crystallography; the adduct represents the first structurally determined carborane of its type, a possible intermediate in the well known conversion of Closo-1,2-C₂B₁₀H₁₂ into the nido-7,8-C₂B₉H₁₂^- anion by bases.

Original language	English
Pages (from-to)	1649-1650
Number of pages	2
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/a903030a
Publication status	Published - 7 Sept 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/a903030a

Fingerprint

Dive into the research topics of 'Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me₂N)₃PNHBNP(NMe₂)₃],O²⁺(C₂B₉H₁₂^-)₂'. Together they form a unique fingerprint.

Cite this

Davidson, M. G., Fox, M. A., Hibbert, T. G., Howard, J. A. K., Mackinnon, A., Neretin, I. S., & Wade, K. (1999). Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me₂N)₃PNHBNP(NMe₂)₃],O²⁺(C₂B₉H₁₂^-)₂. Chemical Communications, (17), 1649-1650. https://doi.org/10.1039/a903030a

Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me₂N)₃PNHBNP(NMe₂)₃],O²⁺(C₂B₉H₁₂^-)₂. / Davidson, Matthew G.; Fox, Mark A.; Hibbert, Thomas G. et al.
In: Chemical Communications, No. 17, 07.09.1999, p. 1649-1650.

Research output: Contribution to journal › Article › peer-review

Davidson, MG, Fox, MA, Hibbert, TG, Howard, JAK, Mackinnon, A, Neretin, IS & Wade, K 1999, 'Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me₂N)₃PNHBNP(NMe₂)₃],O²⁺(C₂B₉H₁₂^-)₂', Chemical Communications, no. 17, pp. 1649-1650. https://doi.org/10.1039/a903030a

Davidson MG, Fox MA, Hibbert TG, Howard JAK, Mackinnon A, Neretin IS et al. Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me₂N)₃PNHBNP(NMe₂)₃],O²⁺(C₂B₉H₁₂^-)₂. Chemical Communications. 1999 Sept 7;(17):1649-1650. doi: 10.1039/a903030a

@article{8f8f2a98289242f095d834aed4f83c40,

title = "Deboronation of ortho-carborane by an iminophosphorane: Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me2N)3PNHBNP(NMe2)3],O2+(C2B9H12-)2",

abstract = "The structures of the adduct nido-C2B10H12·HNP(NMe2)3 and the borenium salt [(Me2N)3PNHBNP(NMe2)3]2O2+(C2B9H12-)2, both obtained from 1,2-C2B10H12 and HNP(NMe2)3, were determined by X-ray crystallography; the adduct represents the first structurally determined carborane of its type, a possible intermediate in the well known conversion of Closo-1,2-C2B10H12 into the nido-7,8-C2B9H12- anion by bases.",

author = "Davidson, \{Matthew G.\} and Fox, \{Mark A.\} and Hibbert, \{Thomas G.\} and Howard, \{Judith A.K.\} and Angus Mackinnon and Neretin, \{Ivan S.\} and Kenneth Wade",

year = "1999",

month = sep,

day = "7",

doi = "10.1039/a903030a",

language = "English",

pages = "1649--1650",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

number = "17",

}

TY - JOUR

T1 - Deboronation of ortho-carborane by an iminophosphorane

T2 - Crystal structures of the novel carborane adduct nido ortho carborane tris(dimethylamino)iminophosphorane complex and the borenium salt [(Me2N)3PNHBNP(NMe2)3],O2+(C2B9H12-)2

AU - Davidson, Matthew G.

AU - Fox, Mark A.

AU - Hibbert, Thomas G.

AU - Howard, Judith A.K.

AU - Mackinnon, Angus

AU - Neretin, Ivan S.

AU - Wade, Kenneth

PY - 1999/9/7

Y1 - 1999/9/7

N2 - The structures of the adduct nido-C2B10H12·HNP(NMe2)3 and the borenium salt [(Me2N)3PNHBNP(NMe2)3]2O2+(C2B9H12-)2, both obtained from 1,2-C2B10H12 and HNP(NMe2)3, were determined by X-ray crystallography; the adduct represents the first structurally determined carborane of its type, a possible intermediate in the well known conversion of Closo-1,2-C2B10H12 into the nido-7,8-C2B9H12- anion by bases.

AB - The structures of the adduct nido-C2B10H12·HNP(NMe2)3 and the borenium salt [(Me2N)3PNHBNP(NMe2)3]2O2+(C2B9H12-)2, both obtained from 1,2-C2B10H12 and HNP(NMe2)3, were determined by X-ray crystallography; the adduct represents the first structurally determined carborane of its type, a possible intermediate in the well known conversion of Closo-1,2-C2B10H12 into the nido-7,8-C2B9H12- anion by bases.

UR - https://www.scopus.com/pages/publications/0033533459

U2 - 10.1039/a903030a

DO - 10.1039/a903030a

M3 - Article

AN - SCOPUS:0033533459

SN - 1359-7345

SP - 1649

EP - 1650

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -