DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Caroline S. Jones; Steven D. Bull; Jonathan M. J. Williams

doi:10.1039/c6ob01854h

DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Caroline S. Jones
, Steven D. Bull
, Jonathan M. J. Williams

Research output: Contribution to journal › Article › peer-review

18 Citations (SciVal)

Abstract

Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.

Original language	English
Pages (from-to)	8452-8456
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	14
Issue number	36
DOIs	https://doi.org/10.1039/c6ob01854h
Publication status	Published - 28 Sept 2016

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title = "DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents",

abstract = "Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.",

author = "Jones, \{Caroline S.\} and Bull, \{Steven D.\} and Williams, \{Jonathan M. J.\}",

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AU - Bull, Steven D.

AU - Williams, Jonathan M. J.

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Y1 - 2016/9/28

N2 - Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.

AB - Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.

UR - https://www.scopus.com/pages/publications/84988336096

UR - http://dx.doi.org/10.1039/c6ob01854h

U2 - 10.1039/c6ob01854h

DO - 10.1039/c6ob01854h

M3 - Article

AN - SCOPUS:84988336096

SN - 1477-0520

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EP - 8456

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 36

ER -

DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Abstract

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