DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Caroline S. Jones, Steven D. Bull, Jonathan M. J. Williams

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.

Original languageEnglish
Pages (from-to)8452-8456
Number of pages5
JournalOrganic and Biomolecular Chemistry
Volume14
Issue number36
DOIs
Publication statusPublished - 28 Sep 2016

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esters
Esters
Salts
salts
Organophosphonates
Nucleophiles
nucleophiles
Sulfonamides
sulfonates
Air
air
phosphoramidic acid

Cite this

DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents. / Jones, Caroline S.; Bull, Steven D.; Williams, Jonathan M. J.

In: Organic and Biomolecular Chemistry, Vol. 14, No. 36, 28.09.2016, p. 8452-8456.

Research output: Contribution to journalArticle

Jones, Caroline S. ; Bull, Steven D. ; Williams, Jonathan M. J. / DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents. In: Organic and Biomolecular Chemistry. 2016 ; Vol. 14, No. 36. pp. 8452-8456.
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