DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Caroline S. Jones; Steven D. Bull; Jonathan M. J. Williams

doi:10.1039/c6ob01854h

DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Caroline S. Jones, Steven D. Bull, Jonathan M. J. Williams

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Abstract

Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.

Original language	English
Pages (from-to)	8452-8456
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	14
Issue number	36
DOIs	https://doi.org/10.1039/c6ob01854h
Publication status	Published - 28 Sept 2016

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abstract = "Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.",

author = "Jones, {Caroline S.} and Bull, {Steven D.} and Williams, {Jonathan M. J.}",

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AU - Williams, Jonathan M. J.

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AB - Air-stable N-sulfonyl and N-phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N- and O-nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.

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ER -

DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents

Abstract

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