Dalton communications. The first undecaruthenium hydrido carbonyl anion; Synthesis and structural characterisation of [Ru11H(CO)27]3-

Philip J. Bailey; Michael A. Beswick; Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; M. Carmen Ramirez De Arellano

doi:10.1039/DT9920003159

Dalton communications. The first undecaruthenium hydrido carbonyl anion; Synthesis and structural characterisation of [Ru₁₁H(CO)₂₇]^3-

Philip J. Bailey, Michael A. Beswick, Brian F.G. Johnson, Jack Lewis, Paul R. Raithby, M. Carmen Ramirez De Arellano

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The cluster trianion [Ru₁₁H(CO)₂₇]^3- has been obtained from the thermolysis of [Ru₃(CO)₁₂] in a methanol-water mixture; an X-ray structure analysis of the [NEt₃(CH₂Ph)]⁺ salt shows that the metal core in the anion is a fragment of hexagonal close packing, which may be described alternatively as the condensation between two octahedra and two trigonal bipyramids sharing common triangular faces.

Original language	English
Pages (from-to)	3159-3160
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	21
DOIs	https://doi.org/10.1039/DT9920003159
Publication status	Published - 31 Dec 1992

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General Chemistry

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abstract = "The cluster trianion [Ru11H(CO)27]3- has been obtained from the thermolysis of [Ru3(CO)12] in a methanol-water mixture; an X-ray structure analysis of the [NEt3(CH2Ph)]+ salt shows that the metal core in the anion is a fragment of hexagonal close packing, which may be described alternatively as the condensation between two octahedra and two trigonal bipyramids sharing common triangular faces.",

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AU - Lewis, Jack

AU - Raithby, Paul R.

AU - De Arellano, M. Carmen Ramirez

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Dalton communications. The first undecaruthenium hydrido carbonyl anion; Synthesis and structural characterisation of [Ru₁₁H(CO)₂₇]^3-

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