Dalton communications. The 'broken cube' polymer structure of (LiBr·thf)∞ (thf = tetrahydrofuran)

Andrew J. Edwards; Michael A. Paver; Paul R. Raithby; Christopher A. Russell; Dominic S. Wright

doi:10.1039/DT9930003265

Dalton communications. The 'broken cube' polymer structure of (LiBr·thf)_∞ (thf = tetrahydrofuran)

Andrew J. Edwards, Michael A. Paver, Paul R. Raithby, Christopher A. Russell, Dominic S. Wright

University of Cambridge

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of GeBr₄ with 2 equivalents of Li₂[C₁₀H₇N] (C₁₀H₇N = 1-naphthylamido dianion) in tetrahydrofuran (thf)-diethyl ether produces (LiBr·thf)_∞ as a product, which has an infinite 'corrugated' ladder structure in the solid state and can be regarded as arising from the association of cubes of (LiBr·thf)₄.

Original language	English
Pages (from-to)	3265-3266
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Issue number	21
DOIs	https://doi.org/10.1039/DT9930003265
Publication status	Published - 1993

ASJC Scopus subject areas

General Chemistry

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title = "Dalton communications. The 'broken cube' polymer structure of (LiBr·thf)∞ (thf = tetrahydrofuran)",

abstract = "The reaction of GeBr4 with 2 equivalents of Li2[C10H7N] (C10H7N = 1-naphthylamido dianion) in tetrahydrofuran (thf)-diethyl ether produces (LiBr·thf)∞ as a product, which has an infinite 'corrugated' ladder structure in the solid state and can be regarded as arising from the association of cubes of (LiBr·thf)4.",

author = "Edwards, {Andrew J.} and Paver, {Michael A.} and Raithby, {Paul R.} and Russell, {Christopher A.} and Wright, {Dominic S.}",

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AU - Russell, Christopher A.

AU - Wright, Dominic S.

PY - 1993

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AB - The reaction of GeBr4 with 2 equivalents of Li2[C10H7N] (C10H7N = 1-naphthylamido dianion) in tetrahydrofuran (thf)-diethyl ether produces (LiBr·thf)∞ as a product, which has an infinite 'corrugated' ladder structure in the solid state and can be regarded as arising from the association of cubes of (LiBr·thf)4.

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Dalton communications. The 'broken cube' polymer structure of (LiBr·thf)_∞ (thf = tetrahydrofuran)

Abstract

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