Dalton communications. Reaction of a side-on co-ordinated carbene ligand with the Wittig reagent

Andrew J. Edwards; Jochem U. Köhler; Jack Lewis; Paul R. Raithby

doi:10.1039/DT9950003251

Dalton communications. Reaction of a side-on co-ordinated carbene ligand with the Wittig reagent

Andrew J. Edwards, Jochem U. Köhler, Jack Lewis, Paul R. Raithby

Durham University

Research output: Contribution to journal › Article › peer-review

Abstract

The 1-methylene-4-phenylcyclohexadiene triosmium complex [Os₃(CO)₉(μ₃-η²:η ²:η²-H₂C=C₆H₅Ph)] has been prepared from the reaction of [Os₃(CO)₉(μ₃-η²:η ¹:η²-C₆H₅Ph)], which contains a side-on co-ordinated carbene group, with the Wittig reagent H₂C=PPh₃; the crystal and molecular structure of the product has been determined by an X-ray diffraction study.

Original language	English
Pages (from-to)	3251-3252
Number of pages	2
Journal	Journal of the Chemical Society, Dalton Transactions
Volume	1995
Issue number	19
DOIs	https://doi.org/10.1039/DT9950003251
Publication status	Published - 31 Dec 1995

ASJC Scopus subject areas

General Chemistry

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abstract = "The 1-methylene-4-phenylcyclohexadiene triosmium complex [Os3(CO)9(μ3-η2:η 2:η2-H2C=C6H5Ph)] has been prepared from the reaction of [Os3(CO)9(μ3-η2:η 1:η2-C6H5Ph)], which contains a side-on co-ordinated carbene group, with the Wittig reagent H2C=PPh3; the crystal and molecular structure of the product has been determined by an X-ray diffraction study.",

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year = "1995",

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T1 - Dalton communications. Reaction of a side-on co-ordinated carbene ligand with the Wittig reagent

AU - Edwards, Andrew J.

AU - Köhler, Jochem U.

AU - Lewis, Jack

AU - Raithby, Paul R.

PY - 1995/12/31

Y1 - 1995/12/31

N2 - The 1-methylene-4-phenylcyclohexadiene triosmium complex [Os3(CO)9(μ3-η2:η 2:η2-H2C=C6H5Ph)] has been prepared from the reaction of [Os3(CO)9(μ3-η2:η 1:η2-C6H5Ph)], which contains a side-on co-ordinated carbene group, with the Wittig reagent H2C=PPh3; the crystal and molecular structure of the product has been determined by an X-ray diffraction study.

AB - The 1-methylene-4-phenylcyclohexadiene triosmium complex [Os3(CO)9(μ3-η2:η 2:η2-H2C=C6H5Ph)] has been prepared from the reaction of [Os3(CO)9(μ3-η2:η 1:η2-C6H5Ph)], which contains a side-on co-ordinated carbene group, with the Wittig reagent H2C=PPh3; the crystal and molecular structure of the product has been determined by an X-ray diffraction study.

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U2 - 10.1039/DT9950003251

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VL - 1995

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JO - Journal of the Chemical Society, Dalton Transactions

JF - Journal of the Chemical Society, Dalton Transactions

IS - 19

ER -

Dalton communications. Reaction of a side-on co-ordinated carbene ligand with the Wittig reagent

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