Cubane-1,3-dicarboxamides as structural isosteres for isophthalamides in hydrogen bond templated interlocked molecules

Sean R. Barlow; Nathan Halcovitch; Geoffrey Akien; Susannah Coote; Nicholas H. Evans

doi:10.1039/D4CC01859A

Cubane-1,3-dicarboxamides as structural isosteres for isophthalamides in hydrogen bond templated interlocked molecules

Sean R. Barlow, Nathan Halcovitch, Geoffrey Akien, Susannah Coote, Nicholas H. Evans

Department of Chemistry

Lancaster University

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterization of the first examples of cubane containing interlocked molecules are reported. Catenanes and rotaxanes have been prepared by hydrogen bond templation with cubane-1,3-dicarboxamides replacing isophthalamide motifs.

Original language	English
Journal	Chemical Communications
Early online date	13 Sept 2024
DOIs	https://doi.org/10.1039/D4CC01859A
Publication status	E-pub ahead of print - 13 Sept 2024

Data Availability Statement

Underlying data for this paper are provided in the ESI.† Electronic copies of NMR spectra (including fid files) will be available upon publication from: DOI: https://doi.org/10.17635/lancaster/researchdata/662 and DOI: https://doi.org/10.17635/lancaster/researchdata/682. Crystallographic data for 4 and 5 have been deposited at CCDC (https://ccdc.cam.ac.uk) under structure numbers 2335982 and 2335981.

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10.1039/D4CC01859ALicence: CC BY

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title = "Cubane-1,3-dicarboxamides as structural isosteres for isophthalamides in hydrogen bond templated interlocked molecules",

abstract = "The synthesis and characterization of the first examples of cubane containing interlocked molecules are reported. Catenanes and rotaxanes have been prepared by hydrogen bond templation with cubane-1,3-dicarboxamides replacing isophthalamide motifs.",

author = "Barlow, {Sean R.} and Nathan Halcovitch and Geoffrey Akien and Susannah Coote and Evans, {Nicholas H.}",

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AU - Barlow, Sean R.

AU - Halcovitch, Nathan

AU - Akien, Geoffrey

AU - Coote, Susannah

AU - Evans, Nicholas H.

PY - 2024/9/13

Y1 - 2024/9/13

N2 - The synthesis and characterization of the first examples of cubane containing interlocked molecules are reported. Catenanes and rotaxanes have been prepared by hydrogen bond templation with cubane-1,3-dicarboxamides replacing isophthalamide motifs.

AB - The synthesis and characterization of the first examples of cubane containing interlocked molecules are reported. Catenanes and rotaxanes have been prepared by hydrogen bond templation with cubane-1,3-dicarboxamides replacing isophthalamide motifs.

U2 - 10.1039/D4CC01859A

DO - 10.1039/D4CC01859A

M3 - Article

SN - 1359-7345

JO - Chemical Communications

JF - Chemical Communications

ER -

Cubane-1,3-dicarboxamides as structural isosteres for isophthalamides in hydrogen bond templated interlocked molecules

Abstract

Data Availability Statement

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