Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)(3)C6H2CNSSN center dot

A Alberola, C S Clarke, D A Haynes, Sofia I Pascu, J M Rawson

Research output: Contribution to journalArticle

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Abstract

The sterically protected dithiadiazolyl radical (F3C)(3)C6H2-CNSSNcenter dot (1) crystallises in two polymorphs: 1 alpha, comprised of monomeric units and 1 beta, containing a mixture of both pi*-pi* dimers and S = 1/2 monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.
Original languageEnglish
Pages (from-to)4726-4728
Number of pages3
JournalChemical Communications
Volume2005
Issue number37
DOIs
Publication statusPublished - 2005

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Polymorphism
Magnetic properties
Crystal structure
Dimers
Monomers

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Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)(3)C6H2CNSSN center dot. / Alberola, A; Clarke, C S; Haynes, D A; Pascu, Sofia I; Rawson, J M.

In: Chemical Communications, Vol. 2005, No. 37, 2005, p. 4726-4728.

Research output: Contribution to journalArticle

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