Crystal structures and magnetic properties of a sterically encumbered dithiadiazolyl radical, 2,4,6-(F3C)(3)C6H2CNSSN center dot

A Alberola, C S Clarke, D A Haynes, Sofia I Pascu, J M Rawson

Research output: Contribution to journalArticle

43 Citations (Scopus)

Abstract

The sterically protected dithiadiazolyl radical (F3C)(3)C6H2-CNSSNcenter dot (1) crystallises in two polymorphs: 1 alpha, comprised of monomeric units and 1 beta, containing a mixture of both pi*-pi* dimers and S = 1/2 monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.
Original languageEnglish
Pages (from-to)4726-4728
Number of pages3
JournalChemical Communications
Volume2005
Issue number37
DOIs
Publication statusPublished - 2005

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