Crystal and molecular structure of bis(di-n-propylammonium) dioxalatodiphenylstannate, [n-Pr2NH2]2[(C2O4)2SnPh2]

Y. Sow, L. Diop, K.C. Molloy, Gabriele Kociok-Kohn, J.D. Ardisson

Research output: Contribution to journalArticle

1 Citation (Scopus)
64 Downloads (Pure)

Abstract

The title compound [n-Pr2NH2]2[(C2O4)2SnPh2] (1) has been synthesized by allowing Ph2SnCl2 to react with [n-Pr2NH2]2C2O4. In 1, characterized using X-ray crystallography, the Sn atom is six-coordinated by two phenyl groups and four oxygen atoms belonging to two asymmetrically chelating oxalate ligands. The geometry is cis octahedral about tin. In the structure of 1, there are two [(C2O4)2SnPh2]2- moieties differentiated by their ∠C-Sn-C angles [105.07° (15°) and 107.43° (16°)]. These similar, but distinct, anions are connected by [n-Pr2NH2]+ cations through N-H···O hydrogen bonds leading to two infinite alternating chains (1) and (2), which loosely assemble via π-π stacking between phenyl groups of adjacent molecules to generate an overall layered structure.

Original languageEnglish
Pages (from-to)221-224
Number of pages4
JournalMain Group Metal Chemistry
Volume36
Issue number5-6
Early online date11 Oct 2013
DOIs
Publication statusPublished - Oct 2013

Fingerprint

Molecular structure
Crystal structure
Atoms
X ray crystallography
Chelation
Tin
Hydrogen bonds
Negative ions
Positive ions
Ligands
Molecules
Oxygen
Geometry

Cite this

Crystal and molecular structure of bis(di-n-propylammonium) dioxalatodiphenylstannate, [n-Pr2NH2]2[(C2O4)2SnPh2]. / Sow, Y.; Diop, L.; Molloy, K.C.; Kociok-Kohn, Gabriele; Ardisson, J.D.

In: Main Group Metal Chemistry, Vol. 36, No. 5-6, 10.2013, p. 221-224.

Research output: Contribution to journalArticle

@article{1bb8ecd3287b4f1090a02461f57b80bd,
title = "Crystal and molecular structure of bis(di-n-propylammonium) dioxalatodiphenylstannate, [n-Pr2NH2]2[(C2O4)2SnPh2]",
abstract = "The title compound [n-Pr2NH2]2[(C2O4)2SnPh2] (1) has been synthesized by allowing Ph2SnCl2 to react with [n-Pr2NH2]2C2O4. In 1, characterized using X-ray crystallography, the Sn atom is six-coordinated by two phenyl groups and four oxygen atoms belonging to two asymmetrically chelating oxalate ligands. The geometry is cis octahedral about tin. In the structure of 1, there are two [(C2O4)2SnPh2]2- moieties differentiated by their ∠C-Sn-C angles [105.07° (15°) and 107.43° (16°)]. These similar, but distinct, anions are connected by [n-Pr2NH2]+ cations through N-H···O hydrogen bonds leading to two infinite alternating chains (1) and (2), which loosely assemble via π-π stacking between phenyl groups of adjacent molecules to generate an overall layered structure.",
author = "Y. Sow and L. Diop and K.C. Molloy and Gabriele Kociok-Kohn and J.D. Ardisson",
year = "2013",
month = "10",
doi = "10.1515/mgmc-2013-0033",
language = "English",
volume = "36",
pages = "221--224",
journal = "Main Group Metal Chemistry",
issn = "0792-1241",
publisher = "De Gruyter",
number = "5-6",

}

TY - JOUR

T1 - Crystal and molecular structure of bis(di-n-propylammonium) dioxalatodiphenylstannate, [n-Pr2NH2]2[(C2O4)2SnPh2]

AU - Sow, Y.

AU - Diop, L.

AU - Molloy, K.C.

AU - Kociok-Kohn, Gabriele

AU - Ardisson, J.D.

PY - 2013/10

Y1 - 2013/10

N2 - The title compound [n-Pr2NH2]2[(C2O4)2SnPh2] (1) has been synthesized by allowing Ph2SnCl2 to react with [n-Pr2NH2]2C2O4. In 1, characterized using X-ray crystallography, the Sn atom is six-coordinated by two phenyl groups and four oxygen atoms belonging to two asymmetrically chelating oxalate ligands. The geometry is cis octahedral about tin. In the structure of 1, there are two [(C2O4)2SnPh2]2- moieties differentiated by their ∠C-Sn-C angles [105.07° (15°) and 107.43° (16°)]. These similar, but distinct, anions are connected by [n-Pr2NH2]+ cations through N-H···O hydrogen bonds leading to two infinite alternating chains (1) and (2), which loosely assemble via π-π stacking between phenyl groups of adjacent molecules to generate an overall layered structure.

AB - The title compound [n-Pr2NH2]2[(C2O4)2SnPh2] (1) has been synthesized by allowing Ph2SnCl2 to react with [n-Pr2NH2]2C2O4. In 1, characterized using X-ray crystallography, the Sn atom is six-coordinated by two phenyl groups and four oxygen atoms belonging to two asymmetrically chelating oxalate ligands. The geometry is cis octahedral about tin. In the structure of 1, there are two [(C2O4)2SnPh2]2- moieties differentiated by their ∠C-Sn-C angles [105.07° (15°) and 107.43° (16°)]. These similar, but distinct, anions are connected by [n-Pr2NH2]+ cations through N-H···O hydrogen bonds leading to two infinite alternating chains (1) and (2), which loosely assemble via π-π stacking between phenyl groups of adjacent molecules to generate an overall layered structure.

UR - http://www.scopus.com/inward/record.url?scp=84892408457&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1515/mgmc-2013-0033

U2 - 10.1515/mgmc-2013-0033

DO - 10.1515/mgmc-2013-0033

M3 - Article

VL - 36

SP - 221

EP - 224

JO - Main Group Metal Chemistry

JF - Main Group Metal Chemistry

SN - 0792-1241

IS - 5-6

ER -