Correction to Kinetics of Asymmetric Transfer Hydrogenation, Catalyst Deactivation, and Inhibition with Noyori Complexes As Revealed by Real-Time High-Resolution FlowNMR Spectroscopy

Andrew M.R. Hall, Peilong Dong, Anna Codina, John P. Lowe, Ulrich Hintermair

Research output: Contribution to journalArticle

Abstract

PAGE 2082 There is an error in the rate equation given in Scheme 2. The correct equation should read as follows: (Formula Presented). PAGE 2084 There are errors in both rate equations given in Figure 8. The equation in the top right of the figure should read the same as the revised equation for Scheme 2 given above, while the equation in the bottom right of the figure should read as follows: (Formula Presented). PAGE 2086 There is an error in the rate equation given in Scheme 3. The correct equation should read as follows: (Formula Presented). PAGE 2087 There is an error in the rate equation given in Figure 11. The correct equation should read the same as the revised equation for Scheme 3 given above. PAGES S20?S23, IN THE SUPPORTING INFORMATION The associated derivations of the above rate equations in the Supporting Information contained the corresponding errors to those in the main article text. The Supporting Information file has been updated with the correct rate equations since publication of this correction. The authors would like to express their thanks to Prof. Guy Lloyd-Jones for bringing these errors to our attention. ASSOCIATED CONTENT Supporting Information The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acscatal.9b02677. Additional experimental data and diagrams; photographs of reaction mixture before and after reaction; details of NMR pulse sequences; calibration methods for selective excitation data; apparatus design, methodology, and synthetic procedures; parameters for kinetic modeling; derivation of rate laws (PDF).

Original languageEnglish
Pages (from-to)7310-7310
Number of pages1
JournalACS Catalysis
Volume9
Issue number8
Early online date16 Jul 2019
DOIs
Publication statusPublished - 2 Aug 2019

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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