Copper(II) fluorophosphates

Edward R Williams, Samuel A Morris, Mark T Weller

Research output: Contribution to journalArticle

13 Citations (Scopus)

Abstract

Eleven new copper fluorophosphate frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CuF2 HPF6 and monovalent metal fluorides as reactants. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra (n = 4–6). Analysis of these structures, in terms of the copper coordination environments and their linkage dimensionalities, shows that these features are dependent on fluoride-content of the reaction medium and, therefore, the level of fluoride ion incorporation into the product materials. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra.
Original languageEnglish
Pages (from-to)10845-10853
JournalDalton Transactions
Volume41
Issue number35
Early online date17 Jul 2012
DOIs
Publication statusPublished - 2012

Fingerprint

fluorophosphate
Fluorides
Copper
Anions
Metals
Single crystals
Ions

Cite this

Williams, E. R., Morris, S. A., & Weller, M. T. (2012). Copper(II) fluorophosphates. Dalton Transactions, 41(35), 10845-10853. https://doi.org/10.1039/c2dt31131c

Copper(II) fluorophosphates. / Williams, Edward R; Morris, Samuel A; Weller, Mark T.

In: Dalton Transactions, Vol. 41, No. 35, 2012, p. 10845-10853.

Research output: Contribution to journalArticle

Williams, ER, Morris, SA & Weller, MT 2012, 'Copper(II) fluorophosphates', Dalton Transactions, vol. 41, no. 35, pp. 10845-10853. https://doi.org/10.1039/c2dt31131c
Williams ER, Morris SA, Weller MT. Copper(II) fluorophosphates. Dalton Transactions. 2012;41(35):10845-10853. https://doi.org/10.1039/c2dt31131c
Williams, Edward R ; Morris, Samuel A ; Weller, Mark T. / Copper(II) fluorophosphates. In: Dalton Transactions. 2012 ; Vol. 41, No. 35. pp. 10845-10853.
@article{5a1ebf3a38584b489a2ee03408efc442,
title = "Copper(II) fluorophosphates",
abstract = "Eleven new copper fluorophosphate frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CuF2 HPF6 and monovalent metal fluorides as reactants. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra (n = 4–6). Analysis of these structures, in terms of the copper coordination environments and their linkage dimensionalities, shows that these features are dependent on fluoride-content of the reaction medium and, therefore, the level of fluoride ion incorporation into the product materials. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra.",
author = "Williams, {Edward R} and Morris, {Samuel A} and Weller, {Mark T}",
year = "2012",
doi = "10.1039/c2dt31131c",
language = "English",
volume = "41",
pages = "10845--10853",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "35",

}

TY - JOUR

T1 - Copper(II) fluorophosphates

AU - Williams, Edward R

AU - Morris, Samuel A

AU - Weller, Mark T

PY - 2012

Y1 - 2012

N2 - Eleven new copper fluorophosphate frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CuF2 HPF6 and monovalent metal fluorides as reactants. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra (n = 4–6). Analysis of these structures, in terms of the copper coordination environments and their linkage dimensionalities, shows that these features are dependent on fluoride-content of the reaction medium and, therefore, the level of fluoride ion incorporation into the product materials. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra.

AB - Eleven new copper fluorophosphate frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CuF2 HPF6 and monovalent metal fluorides as reactants. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra (n = 4–6). Analysis of these structures, in terms of the copper coordination environments and their linkage dimensionalities, shows that these features are dependent on fluoride-content of the reaction medium and, therefore, the level of fluoride ion incorporation into the product materials. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Cu(O,F)n polyhedra.

UR - http://www.scopus.com/inward/record.url?scp=84864967966&partnerID=8YFLogxK

UR - http://dx.doi.org/10.1039/C2DT31131C

U2 - 10.1039/c2dt31131c

DO - 10.1039/c2dt31131c

M3 - Article

VL - 41

SP - 10845

EP - 10853

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 35

ER -