Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

B S Creaven; M F Mahon; J McGinley; A M Moore

doi:10.1016/j.inoche.2005.11.008

Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

B S Creaven, M F Mahon, J McGinley, A M Moore

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

13 Citations (SciVal)

Abstract

The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom. (c) 2005 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	231-234
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	9
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2005.11.008
Publication status	Published - 2006

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ID number: ISI:000235269100027

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10.1016/j.inoche.2005.11.008

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title = "Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction",

abstract = "The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom. (c) 2005 Elsevier B.V. All rights reserved.",

author = "Creaven, {B S} and Mahon, {M F} and J McGinley and Moore, {A M}",

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language = "English",

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journal = "Inorganic Chemistry Communications",

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T1 - Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

AU - Creaven, B S

AU - Mahon, M F

AU - McGinley, J

AU - Moore, A M

N1 - ID number: ISI:000235269100027

PY - 2006

Y1 - 2006

N2 - The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom. (c) 2005 Elsevier B.V. All rights reserved.

AB - The new pyridine-amine ligand, meophdpa (bis(dipyridylmethyl)-4-methoxyaniline) was synthesised and reacted with copper(II) perchlorate. The X-ray crystal structure of the resulting complex revealed a monomeric copper(II) site, with the copper bound to the three ligand nitrogens in a relatively unusual meridional fashion, as well as a chloride and a water molecule. The sixth coordination site was, unexpectedly, occupied by a phenyl ring hydrogen atom. (c) 2005 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.inoche.2005.11.008

DO - 10.1016/j.inoche.2005.11.008

M3 - Article

SN - 1387-7003

VL - 9

SP - 231

EP - 234

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 2

ER -

Copper(II) complex of a tridentate N-donor ligand with unexpected Cu-H interaction

Abstract

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