Copper malonamide complexes and their use in azide-alkyne cycloaddition reactions

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Abstract

We report a rare example of the malonamide functionality being used as a ligand in copper catalysis. We have ligated a homologous series of these O,O-chelating architectures to copper, investigated their structure and exploited them in azide–alkyne cycloaddition reactions for the step-growth synthesis of oligo(triazoles) and in the synthesis of small organic azoles.
Original languageEnglish
Pages (from-to)10253-10258
Number of pages6
JournalDalton Transactions
Volume44
Issue number22
Early online date5 May 2015
DOIs
Publication statusPublished - 14 Jun 2015

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