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Abstract
Treatment of CuCl with 1 equiv of the in situ prepared N-mesityl- substituted diamidocarbene 6-MesDAC produced a mixture of the dimeric and trimeric copper complexes [(6-MesDAC)CuCl] (1) and [(6-MesDAC) (CuCl)] (2). Combining CuCl with isolated, free 6-MesDAC in 1:1 and 3:2 ratios gave just 1 and 2, respectively, while increasing the ratio to >5:1 allowed the isolation of small amounts of the tetrameric copper complex [(6-MesDAC)(CuCl)] (3). Efforts to bring about metathesis reactions of 1 with MOBu (M = Li, Na, K) proved successful only for M = Li to afford the spectroscopically characterized ate product [(6-MesDAC)CuCl·LiOBu·2THF] (5). Attempts to crystallize this species instead gave a 1:1 mixture of 1 and the monomer [(6-MesDAC)CuCl] (6). The X-ray structures of 1-3 and 1 + 6, along with the cation [Cu(6-MesDAC)] (4), have been determined.
Original language | English |
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Pages (from-to) | 2699-2707 |
Number of pages | 9 |
Journal | Inorganic Chemistry |
Volume | 53 |
Issue number | 5 |
Early online date | 11 Feb 2014 |
DOIs | |
Publication status | Published - 3 Mar 2014 |
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Dive into the research topics of 'Copper diamidocarbene complexes: characterization of monomeric to tetrameric species'. Together they form a unique fingerprint.Projects
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500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY
Whittlesey, M. (PI), Danson, M. (CoI), Frost, C. (CoI), Kohn, R. (CoI), Lowe, J. (CoI), Weller, A. (CoI) & Williams, J. (CoI)
Engineering and Physical Sciences Research Council
12/06/06 → 11/06/09
Project: Research council