Coordination polymers based on aluminum(III) porphyrins

Gregory J.E. Davidson; Laura A. Lane; Paul R. Raithby; John E. Warren; Carol V. Robinson; Jeremy K.M. Sanders

doi:10.1021/ic800587y

Coordination polymers based on aluminum(III) porphyrins

Gregory J.E. Davidson, Laura A. Lane, Paul R. Raithby, John E. Warren, Carol V. Robinson, Jeremy K.M. Sanders

Research output: Contribution to journal › Article › peer-review

31 Citations (SciVal)

Abstract

Aluminum(III) porphyrin carboxylate complexes have shown an affinity for a sixth nitrogenous ligand. The use of isonicotinic or nicotinic acid, which offers both a carboxylate and a nitrogen donor in the same molecule, resulted in the formation of one-dimensional (1-D) coordination polymers. The complexes and their linear oligomers have been characterized by ¹H NMR spectroscopy and nanoelectrospray ionization spectrometiy. X-ray analyses confirmed the formation of the 1-D polymers in the solid state.

Original language	English
Pages (from-to)	8721-8726
Number of pages	6
Journal	Inorganic Chemistry
Volume	47
Issue number	19
DOIs	https://doi.org/10.1021/ic800587y
Publication status	Published - 6 Oct 2008

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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abstract = "Aluminum(III) porphyrin carboxylate complexes have shown an affinity for a sixth nitrogenous ligand. The use of isonicotinic or nicotinic acid, which offers both a carboxylate and a nitrogen donor in the same molecule, resulted in the formation of one-dimensional (1-D) coordination polymers. The complexes and their linear oligomers have been characterized by 1H NMR spectroscopy and nanoelectrospray ionization spectrometiy. X-ray analyses confirmed the formation of the 1-D polymers in the solid state.",

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T1 - Coordination polymers based on aluminum(III) porphyrins

AU - Davidson, Gregory J.E.

AU - Lane, Laura A.

AU - Raithby, Paul R.

AU - Warren, John E.

AU - Robinson, Carol V.

AU - Sanders, Jeremy K.M.

PY - 2008/10/6

Y1 - 2008/10/6

N2 - Aluminum(III) porphyrin carboxylate complexes have shown an affinity for a sixth nitrogenous ligand. The use of isonicotinic or nicotinic acid, which offers both a carboxylate and a nitrogen donor in the same molecule, resulted in the formation of one-dimensional (1-D) coordination polymers. The complexes and their linear oligomers have been characterized by 1H NMR spectroscopy and nanoelectrospray ionization spectrometiy. X-ray analyses confirmed the formation of the 1-D polymers in the solid state.

AB - Aluminum(III) porphyrin carboxylate complexes have shown an affinity for a sixth nitrogenous ligand. The use of isonicotinic or nicotinic acid, which offers both a carboxylate and a nitrogen donor in the same molecule, resulted in the formation of one-dimensional (1-D) coordination polymers. The complexes and their linear oligomers have been characterized by 1H NMR spectroscopy and nanoelectrospray ionization spectrometiy. X-ray analyses confirmed the formation of the 1-D polymers in the solid state.

UR - http://www.scopus.com/inward/record.url?scp=54149106102&partnerID=8YFLogxK

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DO - 10.1021/ic800587y

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SP - 8721

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JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 19

ER -

Coordination polymers based on aluminum(III) porphyrins

Abstract

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