TY - JOUR
T1 - Continuous-flow hydrogenation of carbon dioxide to pure formic acid using an Integrated scCO2 process with immobilized catalyst and base
AU - Wesselbaum, Sebastian
AU - Hintermair, Ulrich
AU - Leitner, Walter
PY - 2012/8/20
Y1 - 2012/8/20
N2 - Dual role for CO2: Pure formic acid can be obtained continuously by hydrogenation of CO2 in a single processing unit (see scheme). An immobilized ruthenium organometallic catalyst and a nonvolatile base in an ionic liquid (IL) are combined with supercritical CO2 as both reactant and extractive phase.
AB - Dual role for CO2: Pure formic acid can be obtained continuously by hydrogenation of CO2 in a single processing unit (see scheme). An immobilized ruthenium organometallic catalyst and a nonvolatile base in an ionic liquid (IL) are combined with supercritical CO2 as both reactant and extractive phase.
UR - http://www.scopus.com/inward/record.url?scp=84865100693&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1002/anie.201203185
U2 - 10.1002/anie.201203185
DO - 10.1002/anie.201203185
M3 - Article
SN - 1433-7851
VL - 51
SP - 8585
EP - 8588
JO - Angewandte Chemie International Edition
JF - Angewandte Chemie International Edition
IS - 34
ER -