Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

A D Burrows; M F Mahon; C T F Wong

doi:10.1039/b718961c

Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

A D Burrows
, M F Mahon
, C T F Wong

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

24 Citations (SciVal)

Abstract

[Zn-4(PdCl2)(2)(pydc)(4)(H2O)(4)(THF)(6)] center dot 3.25THF (H(2)pydc = 3,5-pyridinedicarboxylic acid) was formed from the reaction between Zn(NO3)(2) center dot 6H(2)O and trans-[PdCl2(pydc)(2)] in THF, and was shown by X-ray crystallography to have a three-dimensional network structure in which {PdCl2(pydc)(2)}(4-) metalloligands are linked by Zn-2 centres to form a mixed-metal coordination network.

Original language	English
Pages (from-to)	487-489
Number of pages	3
Journal	CrystEngComm
Volume	10
Issue number	5
DOIs	https://doi.org/10.1039/b718961c
Publication status	Published - 2008

Bibliographical note

ID number: ISI:000255263700018

Access to Document

10.1039/b718961c

Cite this

@article{239a195fa9224658875d39b97f87e6f1,

title = "Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc",

abstract = "[Zn-4(PdCl2)(2)(pydc)(4)(H2O)(4)(THF)(6)] center dot 3.25THF (H(2)pydc = 3,5-pyridinedicarboxylic acid) was formed from the reaction between Zn(NO3)(2) center dot 6H(2)O and trans-[PdCl2(pydc)(2)] in THF, and was shown by X-ray crystallography to have a three-dimensional network structure in which \{PdCl2(pydc)(2)\}(4-) metalloligands are linked by Zn-2 centres to form a mixed-metal coordination network.",

author = "Burrows, \{A D\} and Mahon, \{M F\} and Wong, \{C T F\}",

note = "ID number: ISI:000255263700018",

year = "2008",

doi = "10.1039/b718961c",

language = "English",

volume = "10",

pages = "487--489",

journal = "CrystEngComm",

issn = "1466-8033",

publisher = "Royal Society of Chemistry",

number = "5",

}

TY - JOUR

T1 - Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

AU - Burrows, A D

AU - Mahon, M F

AU - Wong, C T F

N1 - ID number: ISI:000255263700018

PY - 2008

Y1 - 2008

N2 - [Zn-4(PdCl2)(2)(pydc)(4)(H2O)(4)(THF)(6)] center dot 3.25THF (H(2)pydc = 3,5-pyridinedicarboxylic acid) was formed from the reaction between Zn(NO3)(2) center dot 6H(2)O and trans-[PdCl2(pydc)(2)] in THF, and was shown by X-ray crystallography to have a three-dimensional network structure in which {PdCl2(pydc)(2)}(4-) metalloligands are linked by Zn-2 centres to form a mixed-metal coordination network.

AB - [Zn-4(PdCl2)(2)(pydc)(4)(H2O)(4)(THF)(6)] center dot 3.25THF (H(2)pydc = 3,5-pyridinedicarboxylic acid) was formed from the reaction between Zn(NO3)(2) center dot 6H(2)O and trans-[PdCl2(pydc)(2)] in THF, and was shown by X-ray crystallography to have a three-dimensional network structure in which {PdCl2(pydc)(2)}(4-) metalloligands are linked by Zn-2 centres to form a mixed-metal coordination network.

UR - https://www.scopus.com/pages/publications/42449110951

U2 - 10.1039/b718961c

DO - 10.1039/b718961c

M3 - Article

SN - 1466-8033

VL - 10

SP - 487

EP - 489

JO - CrystEngComm

JF - CrystEngComm

IS - 5

ER -

Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

Abstract

Bibliographical note

Access to Document

Other files and links

Fingerprint

Cite this