Complexes as metalloligands in network formation: synthesis and characterisation of a mixed-metal coordination network containing palladium and zinc

A D Burrows, M F Mahon, C T F Wong

Research output: Contribution to journalArticle

23 Citations (Scopus)

Abstract

[Zn-4(PdCl2)(2)(pydc)(4)(H2O)(4)(THF)(6)] center dot 3.25THF (H(2)pydc = 3,5-pyridinedicarboxylic acid) was formed from the reaction between Zn(NO3)(2) center dot 6H(2)O and trans-[PdCl2(pydc)(2)] in THF, and was shown by X-ray crystallography to have a three-dimensional network structure in which {PdCl2(pydc)(2)}(4-) metalloligands are linked by Zn-2 centres to form a mixed-metal coordination network.
Original languageEnglish
Pages (from-to)487-489
Number of pages3
JournalCrystEngComm
Volume10
Issue number5
DOIs
Publication statusPublished - 2008

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