Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

B D Roach; R S Forgan; P A Tasker; R M Swart; J Campbell; F E McAllister; A P Stopford; Bridgette J Duncombe

doi:10.1039/c003135f

Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

B D Roach, R S Forgan, P A Tasker, R M Swart, J Campbell, F E McAllister, A P Stopford, Bridgette J Duncombe

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Citations (SciVal)

Abstract

Ligand-ligand interactions in the outer coordination sphere make an important contribution to the effects of 3-substituents on the stabilities of anionic Cu(II) salicylaldoximato complexes [CuL(L-H)](-). When substituents contain a different number of bonds the interpretation of CID tandem mass spectrometry must take into account the ability of ions to redistribute energy acquired in collisions within different numbers of vibrational modes.

Original language	English
Pages (from-to)	5614-5616
Number of pages	3
Journal	Dalton Transactions
Volume	39
Issue number	24
DOIs	https://doi.org/10.1039/c003135f
Publication status	Published - 28 Jun 2010

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abstract = "Ligand-ligand interactions in the outer coordination sphere make an important contribution to the effects of 3-substituents on the stabilities of anionic Cu(II) salicylaldoximato complexes [CuL(L-H)](-). When substituents contain a different number of bonds the interpretation of CID tandem mass spectrometry must take into account the ability of ions to redistribute energy acquired in collisions within different numbers of vibrational modes.",

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T1 - Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

AU - Roach, B D

AU - Forgan, R S

AU - Tasker, P A

AU - Swart, R M

AU - Campbell, J

AU - McAllister, F E

AU - Stopford, A P

AU - Duncombe, Bridgette J

PY - 2010/6/28

Y1 - 2010/6/28

N2 - Ligand-ligand interactions in the outer coordination sphere make an important contribution to the effects of 3-substituents on the stabilities of anionic Cu(II) salicylaldoximato complexes [CuL(L-H)](-). When substituents contain a different number of bonds the interpretation of CID tandem mass spectrometry must take into account the ability of ions to redistribute energy acquired in collisions within different numbers of vibrational modes.

AB - Ligand-ligand interactions in the outer coordination sphere make an important contribution to the effects of 3-substituents on the stabilities of anionic Cu(II) salicylaldoximato complexes [CuL(L-H)](-). When substituents contain a different number of bonds the interpretation of CID tandem mass spectrometry must take into account the ability of ions to redistribute energy acquired in collisions within different numbers of vibrational modes.

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UR - http://dx.doi.org/10.1039/c003135f

U2 - 10.1039/c003135f

DO - 10.1039/c003135f

M3 - Article

SN - 1477-9226

VL - 39

SP - 5614

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JO - Dalton Transactions

JF - Dalton Transactions

IS - 24

ER -

Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

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