TY - JOUR
T1 - Cobalt (II) fluorophosphate frameworks
AU - Armstrong, Jennifer A.
AU - Williams, Edward R.
AU - Weller, Mark T.
PY - 2012
Y1 - 2012
N2 - Nine new cobalt fluorophosphates frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CoF3 and HPF6 as reactants in combination with Group I/II metal hydroxides and organic cations as templating species. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO3F, PO2(OH,F)2 and Co(O,F)n polyhedra (n = 5–6) including μ2, μ3 and μ4 bridging fluoride. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Co(O,F)n polyhedra.
AB - Nine new cobalt fluorophosphates frameworks have been synthesised hydrothermally in a fluoride-rich medium, through the use of CoF3 and HPF6 as reactants in combination with Group I/II metal hydroxides and organic cations as templating species. Products have been structurally characterised using single crystal X-ray diffraction. Reaction in fluoride-rich conditions produces chain, layer and three dimensional framework structures containing new and unusual structural features based on the linking of PO3F, PO2(OH,F)2 and Co(O,F)n polyhedra (n = 5–6) including μ2, μ3 and μ4 bridging fluoride. Structures exhibiting inter-layer spaces and channels frequently have these lined by terminal fluoride anions of the PO3F, PO2(OH,F)2 and Co(O,F)n polyhedra.
UR - http://www.scopus.com/inward/record.url?scp=84868668149&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1039/c2dt31734f
U2 - 10.1039/c2dt31734f
DO - 10.1039/c2dt31734f
M3 - Article
SN - 1477-9226
VL - 41
SP - 14180
EP - 14187
JO - Dalton Transactions
JF - Dalton Transactions
IS - 46
ER -