Chiral Phthalocyanines through Axial Coordination

Dora M. Răsădean; Tiberiu M. Gianga; Alexander H. Swan; Gabriele Kociok-köhn; G. Dan Pantoş

doi:10.1021/acs.orglett.8b00851

Chiral Phthalocyanines through Axial Coordination

Dora M. Răsădean, Tiberiu M. Gianga, Alexander H. Swan, Gabriele Kociok-köhn, G. Dan Pantoş

Research output: Contribution to journal › Article › peer-review

9 Citations (SciVal)

203 Downloads (Pure)

Abstract

A novel approach to axially induce chirality on silicon phthalocyanines via a microwave-assisted route is reported. CD analysis provides spectroscopic evidence that chirality is transferred onto both Soret and Q-bands of the phthalocyanine core. A chiral naphthalenediimide ligand was found to induce the largest Cotton effect on the macrocycle absorptions.

Original language	English
Pages (from-to)	2645-2648
Number of pages	4
Journal	Organic Letters
Volume	20
Issue number	9
Early online date	20 Apr 2018
DOIs	https://doi.org/10.1021/acs.orglett.8b00851
Publication status	Published - 4 May 2018

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/acs.orglett.8b00851

Pc_paper_revd_10Apr_GDP
This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.8b008.
Accepted author manuscript, 599 KB

Cite this

@article{589f31d8bfbb4a529d25b3c1fa47de0e,

title = "Chiral Phthalocyanines through Axial Coordination",

abstract = "A novel approach to axially induce chirality on silicon phthalocyanines via a microwave-assisted route is reported. CD analysis provides spectroscopic evidence that chirality is transferred onto both Soret and Q-bands of the phthalocyanine core. A chiral naphthalenediimide ligand was found to induce the largest Cotton effect on the macrocycle absorptions.",

author = "R{\u a}s{\u a}dean, \{Dora M.\} and Gianga, \{Tiberiu M.\} and Swan, \{Alexander H.\} and Gabriele Kociok-k{\"o}hn and Panto{\c s}, \{G. Dan\}",

year = "2018",

month = may,

day = "4",

doi = "10.1021/acs.orglett.8b00851",

language = "English",

volume = "20",

pages = "2645--2648",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "9",

}

TY - JOUR

T1 - Chiral Phthalocyanines through Axial Coordination

AU - Răsădean, Dora M.

AU - Gianga, Tiberiu M.

AU - Swan, Alexander H.

AU - Kociok-köhn, Gabriele

AU - Pantoş, G. Dan

PY - 2018/5/4

Y1 - 2018/5/4

N2 - A novel approach to axially induce chirality on silicon phthalocyanines via a microwave-assisted route is reported. CD analysis provides spectroscopic evidence that chirality is transferred onto both Soret and Q-bands of the phthalocyanine core. A chiral naphthalenediimide ligand was found to induce the largest Cotton effect on the macrocycle absorptions.

AB - A novel approach to axially induce chirality on silicon phthalocyanines via a microwave-assisted route is reported. CD analysis provides spectroscopic evidence that chirality is transferred onto both Soret and Q-bands of the phthalocyanine core. A chiral naphthalenediimide ligand was found to induce the largest Cotton effect on the macrocycle absorptions.

UR - https://www.scopus.com/pages/publications/85046692303

U2 - 10.1021/acs.orglett.8b00851

DO - 10.1021/acs.orglett.8b00851

M3 - Article

SN - 1523-7060

VL - 20

SP - 2645

EP - 2648

JO - Organic Letters

JF - Organic Letters

IS - 9

ER -

Chiral Phthalocyanines through Axial Coordination

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this