TY - JOUR
T1 - Chemistry of triangulo and linear triosmium cyclopentadienyl cluster compounds
T2 - The X-ray structures of [Os3(CO)10(η 5-C5H5)Cl] and [Os3(CO) 8(η5-C5H5)(μ-Cl)]
AU - Gallop, Mark A.
AU - Johnson, Brian F. G.
AU - Lewis, Jack
AU - Raithby, Paul R.
PY - 1986/12/31
Y1 - 1986/12/31
N2 - The cationic triangulo-complex [Os3(CO)10(η 5-C5H5)][BF4] reacts with X - (X=H, Cl) to afford linear triosmium cluster compounds, [Os 3(CO)10(η5-C5H5)X], characterised by X-ray crystallography for X=Cl; on heating [Os 3(CO)10-(η5-C5H5)Cl] is converted into the triangulo-cluster [OS3(CO)8(η 5-C5H5)(μ-Cl)] which, on the basic of an X-ray analysis, contains an unusually short chloride-bridged osmium-osmium distance.
AB - The cationic triangulo-complex [Os3(CO)10(η 5-C5H5)][BF4] reacts with X - (X=H, Cl) to afford linear triosmium cluster compounds, [Os 3(CO)10(η5-C5H5)X], characterised by X-ray crystallography for X=Cl; on heating [Os 3(CO)10-(η5-C5H5)Cl] is converted into the triangulo-cluster [OS3(CO)8(η 5-C5H5)(μ-Cl)] which, on the basic of an X-ray analysis, contains an unusually short chloride-bridged osmium-osmium distance.
UR - http://www.scopus.com/inward/record.url?scp=37049081106&partnerID=8YFLogxK
U2 - 10.1039/C39860000706
DO - 10.1039/C39860000706
M3 - Article
AN - SCOPUS:37049081106
SN - 0022-4936
SP - 706
EP - 708
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 9
ER -