Characterisation of an osmium cluster carbonyl containing a weakly co-ordinated amine ligand; X-ray crystal and molecular structure of [Os 3(CO)9(NO)2(NMe3)]

Brian F.G. Johnson; Jack Lewis; Paul R. Raithby; Camillo Zuccaro

doi:10.1039/C39790000916

Characterisation of an osmium cluster carbonyl containing a weakly co-ordinated amine ligand; X-ray crystal and molecular structure of [Os ₃(CO)₉(NO)₂(NMe₃)]

Brian F.G. Johnson
, Jack Lewis
, Paul R. Raithby
, Camillo Zuccaro

University Chemical Loboratory

Research output: Contribution to journal › Article › peer-review

Abstract

The X-ray structure of the first trialkylamine metal cluster, [Os ₃(CO)₉(NO)₂(NMe₃)], has been determined; the large steric requirements of the trialkylamine is reflected in the long Os-N distance of the co-ordinated group.

Original language	English
Pages (from-to)	916-917
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	20
DOIs	https://doi.org/10.1039/C39790000916
Publication status	Published - 31 Dec 1979

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39790000916

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Characterisation of an osmium cluster carbonyl containing a weakly co-ordinated amine ligand; X-ray crystal and molecular structure of [Os ₃(CO)₉(NO)₂(NMe₃)]. / Johnson, Brian F.G.; Lewis, Jack; Raithby, Paul R. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 20, 31.12.1979, p. 916-917.

Research output: Contribution to journal › Article › peer-review

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title = "Characterisation of an osmium cluster carbonyl containing a weakly co-ordinated amine ligand; X-ray crystal and molecular structure of [Os 3(CO)9(NO)2(NMe3)]",

abstract = "The X-ray structure of the first trialkylamine metal cluster, [Os 3(CO)9(NO)2(NMe3)], has been determined; the large steric requirements of the trialkylamine is reflected in the long Os-N distance of the co-ordinated group.",

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year = "1979",

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AU - Johnson, Brian F.G.

AU - Lewis, Jack

AU - Raithby, Paul R.

AU - Zuccaro, Camillo

PY - 1979/12/31

Y1 - 1979/12/31

N2 - The X-ray structure of the first trialkylamine metal cluster, [Os 3(CO)9(NO)2(NMe3)], has been determined; the large steric requirements of the trialkylamine is reflected in the long Os-N distance of the co-ordinated group.

AB - The X-ray structure of the first trialkylamine metal cluster, [Os 3(CO)9(NO)2(NMe3)], has been determined; the large steric requirements of the trialkylamine is reflected in the long Os-N distance of the co-ordinated group.

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DO - 10.1039/C39790000916

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ER -

Characterisation of an osmium cluster carbonyl containing a weakly co-ordinated amine ligand; X-ray crystal and molecular structure of [Os ₃(CO)₉(NO)₂(NMe₃)]

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