TY - JOUR
T1 - Cerium(IV) fluoride and fluoride-arsenate frameworks
AU - Rouse, Jessica
AU - Weller, Mark T.
PY - 2009
Y1 - 2009
N2 - Five new cerium (IV) fluoride and fluoride-arsenate framework structures have been synthesised hydrothermally using CeF as a fluoride source. Cs[CeF[F·HO]] (I) consists of layers, formed from linked Ce(F,O) polyhedra cross-linked by hydrogen bonding that defines large channels containing the caesium ions. [(NH)(HO)][Ce (AsO)(HO)F] (II), has an open framework structure with large channels filled with NH cations and HO molecules. Ce[AsO ]F (III) and Ce[AsO]F[HO] (IV) exhibit two types of bridging (Ce-O-Ce and Ce-F-Ce) bonds between Ce(O,F) polyhedra, and (NH)[CeF(AsO)] (V), is isostructural with the previously reported fluoride-phosphate (NH )[CeF(PO)] (R. B. Yu, D. Wang, T. Takei, N. Kumada, H. Koizumi and N. Kinomura, J. Solid State Chem., 2001, 157, 180).1
AB - Five new cerium (IV) fluoride and fluoride-arsenate framework structures have been synthesised hydrothermally using CeF as a fluoride source. Cs[CeF[F·HO]] (I) consists of layers, formed from linked Ce(F,O) polyhedra cross-linked by hydrogen bonding that defines large channels containing the caesium ions. [(NH)(HO)][Ce (AsO)(HO)F] (II), has an open framework structure with large channels filled with NH cations and HO molecules. Ce[AsO ]F (III) and Ce[AsO]F[HO] (IV) exhibit two types of bridging (Ce-O-Ce and Ce-F-Ce) bonds between Ce(O,F) polyhedra, and (NH)[CeF(AsO)] (V), is isostructural with the previously reported fluoride-phosphate (NH )[CeF(PO)] (R. B. Yu, D. Wang, T. Takei, N. Kumada, H. Koizumi and N. Kinomura, J. Solid State Chem., 2001, 157, 180).1
UR - http://www.scopus.com/inward/record.url?scp=70450180712&partnerID=8YFLogxK
UR - http://dx.doi.org/10.1039/b912262a
U2 - 10.1039/b912262a
DO - 10.1039/b912262a
M3 - Article
AN - SCOPUS:70450180712
SN - 1477-9226
VL - 2009
SP - 10330
EP - 10337
JO - Dalton Transactions
JF - Dalton Transactions
IS - 46
ER -