catena-Poly triphenyltin(IV) -mu-phenylphosphinato-kappa(2)O:O '

T Diop, L Diop, Gabriele Kociok-Kohn, Kieran C Molloy, H Stoeckli-Evans

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In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)-(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2)(-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H center dot center dot center dot pi interactions, forming a two-dimensional network lying parallel to (001).
Original languageEnglish
Pages (from-to)M1674-U1749
JournalActa Crystallographica Section E-Structure Reports Online
Issue number12
Publication statusPublished - Dec 2011


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