Abstract
[2,3]-Sigmatropic rearrangement processes of allylic ylides or their equivalents can be applied to a variety of different substrates and generate products of wide interest/applicability to organic synthesis. This review describes the development and applications of stereoselective [2,3]-rearrangement reactions in which a substoichiometric amount of a catalyst is used in either the formation of the reactive intermediate or the [2,3]-rearrangement step itself.
Original language | English |
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Pages (from-to) | 7446-7479 |
Number of pages | 34 |
Journal | ACS Catalysis |
Volume | 5 |
Issue number | 12 |
DOIs | |
Publication status | Published - 29 Oct 2015 |
Keywords
- allylic ammonium ylides
- allylic N-oxides
- allylic oxonium ylides
- allylic sulfonium ylides
- allylic sulfoxides
- O-propargylic oximes
- stereoselective catalysis
- [2,3]-rearrangement
ASJC Scopus subject areas
- Catalysis