Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 12807-12810 |
| Number of pages | 4 |
| Journal | Chemical Communications |
| Volume | 51 |
| Issue number | 64 |
| Early online date | 6 Jul 2015 |
| DOIs | |
| Publication status | Published - 18 Aug 2015 |
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Catalytic meta-selective C–H functionalization to construct quaternary carbon centres. / Paterson, Andrew; St. John-Campbell , Sahra ; Mahon, Mary; Press, N J; Frost, Christopher.
In: Chemical Communications, Vol. 51, No. 64, 18.08.2015, p. 12807-12810.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Catalytic meta-selective C–H functionalization to construct quaternary carbon centres
AU - Paterson, Andrew
AU - St. John-Campbell , Sahra
AU - Mahon, Mary
AU - Press, N J
AU - Frost, Christopher
PY - 2015/8/18
Y1 - 2015/8/18
N2 - A catalytic meta-selective C–H functionalization of 2-phenylpyridines using a range of tertiary halides is described. The protocol is simple to perform and uses commercially available reagents to construct challenging quaternary carbon centres in a regioselective manner. Preliminary studies suggest the C–H functionalization proceeds through a radical process directed via a remote σ-activation.
AB - A catalytic meta-selective C–H functionalization of 2-phenylpyridines using a range of tertiary halides is described. The protocol is simple to perform and uses commercially available reagents to construct challenging quaternary carbon centres in a regioselective manner. Preliminary studies suggest the C–H functionalization proceeds through a radical process directed via a remote σ-activation.
UR - http://dx.doi.org/10.1039/C5CC03951G
UR - http://pubs.rsc.org/en/Content/ArticleLanding/2015/CC/C5CC03951G#!divAbstract
U2 - 10.1039/C5CC03951G
DO - 10.1039/C5CC03951G
M3 - Article
VL - 51
SP - 12807
EP - 12810
JO - Chemical communications (Cambridge, England)
JF - Chemical communications (Cambridge, England)
SN - 1359-7345
IS - 64
ER -