Catalytic hydrodefluorination of pentafluorobenzene by Ru(NHC)-(PPh3)(2)(CO)H-2 : A nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity

J A Panetier; S A Macgregor; Michael K Whittlesey

doi:10.1002/anie.201006789

Catalytic hydrodefluorination of pentafluorobenzene by Ru(NHC)-(PPh3)(2)(CO)H-2 : A nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity

J A Panetier, S A Macgregor, Michael K Whittlesey

Department of Chemistry

Research output: Contribution to journal › Article › peer-review

72 Citations (SciVal)

Original language	English
Pages (from-to)	2783-2786
Number of pages	4
Journal	Angewandte Chemie International Edition
Volume	50
Issue number	12
DOIs	https://doi.org/10.1002/anie.201006789
Publication status	Published - 2011

Keywords

fluoroarenes
density functional calculations
ruthenium
hydrodefluorination
C-F activation

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10.1002/anie.201006789

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Catalytic hydrodefluorination of pentafluorobenzene by Ru(NHC)-(PPh3)(2)(CO)H-2 : A nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity. / Panetier, J A; Macgregor, S A; Whittlesey, Michael K.
In: Angewandte Chemie International Edition, Vol. 50, No. 12, 2011, p. 2783-2786.

Research output: Contribution to journal › Article › peer-review

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Catalytic hydrodefluorination of pentafluorobenzene by Ru(NHC)-(PPh3)(2)(CO)H-2 : A nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity

Keywords

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500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY

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Catalytic hydrodefluorination of pentafluorobenzene by Ru(NHC)-(PPh3)(2)(CO)H-2 : A nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity

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500 MHZ NMR SPECTROMETER TO SUPPORT ORGANIC, BIO-ORGANIC AND INORGANIC CHEMISTRY

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