Carbon dioxide entrapment in an organic molecular host

Tia Jacobs; Vincent J. Smith; Lynne H. Thomas; Leonard J. Barbour

doi:10.1039/c3cc46784h

Carbon dioxide entrapment in an organic molecular host

Tia Jacobs
, Vincent J. Smith
, Lynne H. Thomas
, Leonard J. Barbour

Department of Chemistry

Stellenbosch University

Research output: Contribution to journal › Article › peer-review

21 Citations (SciVal)

Abstract

4-Phenoxyphenol crystallises to yield discrete 60 Å³ cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO₂ pressure.

Original language	English
Pages (from-to)	85-87
Journal	Chemical Communications
Volume	50
Issue number	1
Early online date	23 Oct 2013
DOIs	https://doi.org/10.1039/c3cc46784h
Publication status	Published - 4 Jan 2014

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title = "Carbon dioxide entrapment in an organic molecular host",

abstract = "4-Phenoxyphenol crystallises to yield discrete 60 {\AA}3 cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO2 pressure.",

author = "Tia Jacobs and Smith, \{Vincent J.\} and Thomas, \{Lynne H.\} and Barbour, \{Leonard J.\}",

year = "2014",

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doi = "10.1039/c3cc46784h",

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AU - Jacobs, Tia

AU - Smith, Vincent J.

AU - Thomas, Lynne H.

AU - Barbour, Leonard J.

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Y1 - 2014/1/4

N2 - 4-Phenoxyphenol crystallises to yield discrete 60 Å3 cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO2 pressure.

AB - 4-Phenoxyphenol crystallises to yield discrete 60 Å3 cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO2 pressure.

UR - https://www.scopus.com/pages/publications/84888624145

UR - http://dx.doi.org/10.1039/c3cc46784h

U2 - 10.1039/c3cc46784h

DO - 10.1039/c3cc46784h

M3 - Article

SN - 1359-7345

VL - 50

SP - 85

EP - 87

JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

Carbon dioxide entrapment in an organic molecular host

Abstract

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