Carbon dioxide entrapment in an organic molecular host

Tia Jacobs; Vincent J. Smith; Lynne H. Thomas; Leonard J. Barbour

doi:10.1039/c3cc46784h

Carbon dioxide entrapment in an organic molecular host

Tia Jacobs, Vincent J. Smith, Lynne H. Thomas, Leonard J. Barbour

Department of Chemistry

Stellenbosch University

Research output: Contribution to journal › Article › peer-review

18 Citations (SciVal)

Abstract

4-Phenoxyphenol crystallises to yield discrete 60 Å³ cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO₂ pressure.

Original language	English
Pages (from-to)	85-87
Journal	Chemical Communications
Volume	50
Issue number	1
Early online date	23 Oct 2013
DOIs	https://doi.org/10.1039/c3cc46784h
Publication status	Published - 4 Jan 2014

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title = "Carbon dioxide entrapment in an organic molecular host",

abstract = "4-Phenoxyphenol crystallises to yield discrete 60 {\AA}3 cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO2 pressure.",

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AU - Thomas, Lynne H.

AU - Barbour, Leonard J.

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N2 - 4-Phenoxyphenol crystallises to yield discrete 60 Å3 cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO2 pressure.

AB - 4-Phenoxyphenol crystallises to yield discrete 60 Å3 cavities that are capable of enclathrating small solvent molecules; the cavities are capped by constricted 6-membered hydrogen-bonded rings and these potential apertures do not appear to facilitate gated porosity when the material is subjected to static CO2 pressure.

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JO - Chemical Communications

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Carbon dioxide entrapment in an organic molecular host

Abstract

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