Can slow-moving ions explain hysteresis in the current–voltage curves of perovskite solar cells?

Giles Richardson, Simon O'Kane, Ralf Niemann, Timo Peltola, Jamie Foster, Petra Cameron, Alison Walker

Research output: Contribution to journalArticle

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Abstract

The hypothesis that ion motion is responsible for anomalous hysteresis in the current–voltage curves of perovskite solar cells is investigated through a combination of electrical transport modelling and experimental measurements. In a combined computational and experimental study, good agreement is obtained between experiment and the results of a charge transport model covering mixed ionic-electronic conduction. Our model couples electrons, holes and defect mediated ion motion suggesting that slow moving ions are indeed the origin of the hysteresis. The magnitude of the ion diffusion coefficient required to match experiment and theory, ∼10−12 cm2 s−1, depends on the cell, but is similar to that predicted by microscopic theory of vacancy mediated diffusion. The investigation is extended to preconditioning procedures which are known to substantially influence the hysteresis. The method developed for solving the stiff equations in the drift diffusion model is widely applicable to other double layer problems occurring in electrochemical applications such as the evolution of transmembrane potentials in living cells.
LanguageEnglish
Pages1476-1485
Number of pages10
JournalEnergy & Environmental Science
Volume9
Early online date12 Feb 2016
DOIs
StatusPublished - 1 Apr 2016

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perovskite
hysteresis
Hysteresis
Ions
ion
Electric potential
Vacancies
defect
Charge transfer
experimental study
experiment
Experiments
Cells
electron
Defects
solar cell
Perovskite solar cells
Electrons
modeling

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Can slow-moving ions explain hysteresis in the current–voltage curves of perovskite solar cells? / Richardson, Giles; O'Kane, Simon; Niemann, Ralf; Peltola, Timo; Foster, Jamie; Cameron, Petra; Walker, Alison.

In: Energy & Environmental Science, Vol. 9, 01.04.2016, p. 1476-1485.

Research output: Contribution to journalArticle

Richardson, Giles ; O'Kane, Simon ; Niemann, Ralf ; Peltola, Timo ; Foster, Jamie ; Cameron, Petra ; Walker, Alison. / Can slow-moving ions explain hysteresis in the current–voltage curves of perovskite solar cells?. In: Energy & Environmental Science. 2016 ; Vol. 9. pp. 1476-1485.
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