Calculation of solubility parameters from inverse gas chromatography

Research output: Contribution to journalConference article

Abstract

One frequent industrial use of the solubility parameter concept is in the prediction of compatibility in polymer-plasticizer systems. As dictated by their conditions of use, the compounds used as plasticizers are usually large, involatile organic molecules such as the alkyl phthalates so that the above comments are also applicable to their δ2 values. Thus, it was of interest to determine the applicability of the IGC method to these compounds. Experimental data indicate that for the less polar compounds, the best agreement with literature values is observed with the results from the alkane probes but this does not hold for the polar NMP (N-Methyl Pyrrolidone) and DEBH (Dibutyl-2-Ethyl Hexamide). Were polar forces becoming increasingly important at higher δ1 values, the graphs would be expected to show an increase in slope and this is indeed found for the polar components.

Original languageEnglish
Pages (from-to)1009-1013
Number of pages5
JournalPolymeric Materials Science and Engineering
Volume58
Publication statusPublished - 1 Dec 1988
EventThird Chemical Congress of North America - Toronto, Ont, Can
Duration: 6 Jun 198810 Jun 1988

ASJC Scopus subject areas

  • Chemical Engineering (miscellaneous)
  • Polymers and Plastics

Cite this

Calculation of solubility parameters from inverse gas chromatography. / Price, G. J.

In: Polymeric Materials Science and Engineering, Vol. 58, 01.12.1988, p. 1009-1013.

Research output: Contribution to journalConference article

@article{c731336639534bbc8d022c8bdbcfb28f,
title = "Calculation of solubility parameters from inverse gas chromatography",
abstract = "One frequent industrial use of the solubility parameter concept is in the prediction of compatibility in polymer-plasticizer systems. As dictated by their conditions of use, the compounds used as plasticizers are usually large, involatile organic molecules such as the alkyl phthalates so that the above comments are also applicable to their δ2 values. Thus, it was of interest to determine the applicability of the IGC method to these compounds. Experimental data indicate that for the less polar compounds, the best agreement with literature values is observed with the results from the alkane probes but this does not hold for the polar NMP (N-Methyl Pyrrolidone) and DEBH (Dibutyl-2-Ethyl Hexamide). Were polar forces becoming increasingly important at higher δ1 values, the graphs would be expected to show an increase in slope and this is indeed found for the polar components.",
author = "Price, {G. J.}",
year = "1988",
month = "12",
day = "1",
language = "English",
volume = "58",
pages = "1009--1013",
journal = "Polymeric Materials Science and Engineering",
issn = "0743-0515",
publisher = "American Chemical Society",

}

TY - JOUR

T1 - Calculation of solubility parameters from inverse gas chromatography

AU - Price, G. J.

PY - 1988/12/1

Y1 - 1988/12/1

N2 - One frequent industrial use of the solubility parameter concept is in the prediction of compatibility in polymer-plasticizer systems. As dictated by their conditions of use, the compounds used as plasticizers are usually large, involatile organic molecules such as the alkyl phthalates so that the above comments are also applicable to their δ2 values. Thus, it was of interest to determine the applicability of the IGC method to these compounds. Experimental data indicate that for the less polar compounds, the best agreement with literature values is observed with the results from the alkane probes but this does not hold for the polar NMP (N-Methyl Pyrrolidone) and DEBH (Dibutyl-2-Ethyl Hexamide). Were polar forces becoming increasingly important at higher δ1 values, the graphs would be expected to show an increase in slope and this is indeed found for the polar components.

AB - One frequent industrial use of the solubility parameter concept is in the prediction of compatibility in polymer-plasticizer systems. As dictated by their conditions of use, the compounds used as plasticizers are usually large, involatile organic molecules such as the alkyl phthalates so that the above comments are also applicable to their δ2 values. Thus, it was of interest to determine the applicability of the IGC method to these compounds. Experimental data indicate that for the less polar compounds, the best agreement with literature values is observed with the results from the alkane probes but this does not hold for the polar NMP (N-Methyl Pyrrolidone) and DEBH (Dibutyl-2-Ethyl Hexamide). Were polar forces becoming increasingly important at higher δ1 values, the graphs would be expected to show an increase in slope and this is indeed found for the polar components.

UR - http://www.scopus.com/inward/record.url?scp=0024122495&partnerID=8YFLogxK

M3 - Conference article

VL - 58

SP - 1009

EP - 1013

JO - Polymeric Materials Science and Engineering

JF - Polymeric Materials Science and Engineering

SN - 0743-0515

ER -