Calcium stannyl formation by organostannane dehydrogenation

Research output: Contribution to journalArticle

Abstract

Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.

Original languageEnglish
Pages (from-to)12964-12967
Number of pages4
JournalChemical Communications
Volume55
Issue number86
Early online date3 Oct 2019
DOIs
Publication statusPublished - 7 Nov 2019

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

Cite this

Calcium stannyl formation by organostannane dehydrogenation. / Morris, Louis J.; Hill, Michael S.; Manners, Ian; Mcmullin, Claire L.; Mahon, Mary F.; Rajabi, Nasir A.

In: Chemical Communications, Vol. 55, No. 86, 07.11.2019, p. 12964-12967.

Research output: Contribution to journalArticle

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