Calcium stannyl formation by organostannane dehydrogenation

Louis J. Morris; Michael S. Hill; Ian Manners; Claire L. Mcmullin; Mary F. Mahon; Nasir A. Rajabi

doi:10.1039/c9cc07289f

Calcium stannyl formation by organostannane dehydrogenation

Louis J. Morris, Michael S. Hill, Ian Manners, Claire L. Mcmullin, Mary F. Mahon, Nasir A. Rajabi

Department of Chemistry

University of Victoria

Research output: Contribution to journal › Article › peer-review

14 Citations (SciVal)

Abstract

Reaction of the dimeric calcium hydride, [(BDI)CaH]₂ (1), with Ph₃SnH ensues with elimination of H₂ to provide [(BDI)Ca-μ₂-H-(SnPh₃)Ca(BDI)] (3) and [(BDI)Ca(SnPh₃)]₂ (4) alongside dismutation to Ph₄Sn, H₂ and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph₃SnH and with retention of dinuclear species throughout the reactions.

Original language	English
Pages (from-to)	12964-12967
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	86
Early online date	3 Oct 2019
DOIs	https://doi.org/10.1039/c9cc07289f
Publication status	Published - 7 Nov 2019

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/c9cc07289fLicence: CC BY

Cite this

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title = "Calcium stannyl formation by organostannane dehydrogenation",

abstract = "Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.",

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T1 - Calcium stannyl formation by organostannane dehydrogenation

AU - Morris, Louis J.

AU - Hill, Michael S.

AU - Manners, Ian

AU - Mcmullin, Claire L.

AU - Mahon, Mary F.

AU - Rajabi, Nasir A.

PY - 2019/11/7

Y1 - 2019/11/7

N2 - Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.

AB - Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.

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JO - Chemical Communications

JF - Chemical Communications

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ER -

Calcium stannyl formation by organostannane dehydrogenation

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Nucleophilic alkaline earth boryls: from conception and theory to application

Balena High Performance Computing (HPC) System

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Calcium stannyl formation by organostannane dehydrogenation

Abstract

ASJC Scopus subject areas

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Nucleophilic alkaline earth boryls: from conception and theory to application

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Balena High Performance Computing (HPC) System

High Performance Computing (HPC) Facility

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